Poly[1-ethyl-3-methylimidazolium [tri-μ-isothiocyanato-manganate(II)]]

6533b870fe1ef96bd12cf33d

RESEARCH PRODUCT

Poly[1-ethyl-3-methylimidazolium [tri-μ-isothiocyanato-manganate(II)]]

Tim Peppel Martin Köckerling

subject

crystal structure thiocyanate Thiocyanate Manganate chemistry.chemical_element Thio-02 engineering and technology Crystal structure Manganese 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound network structure chemistry Bromide Ionic liquid manganese lcsh:QD901-999 Salt metathesis reaction lcsh:Crystallography 0210 nano-technology ionic liquid

description

The title compound, {(C9H11N2)[Mn(NCS)3]} n , has been obtained as a side product of the salt metathesis reaction of 1-ethyl-3-methylimidazolium bromide, (EMIm)Br, and K2[Mn(NCS)4]. The structure consists of discrete 1-ethyl-3-methylimidazolium cations and an anionic two-dimensional network of manganese(II)-based complex anions, interconnected by thiocyanate ions. Every Mn2+ ion is coordinated by three S atoms of three NCS− ions and three N atoms of further three NCS− ions in a meridional octahedral fashion.

year	journal	country	edition	language
2019-12-17	IUCrData

https://doi.org/10.1107/s2414314619016596

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