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RESEARCH PRODUCT
Hybrid organic-inorganic mononuclear lanthanoid single ion magnets
Patricio Hermosilla-ibáñezWalter Cañon-mancisidorMatias Zapata-lizamaGuillermo Mínguez EspallargasCarlos CruzDiego Venegas-yazigisubject
LanthanideMaterials scienceSingle ionField (physics)010405 organic chemistryMetals and AlloysGeneral ChemistryQuímica010402 general chemistryHybrid approach01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsMagnetOrganic inorganicMaterials ChemistryCeramics and CompositesPhysical chemistryMaterialsdescription
The first family of hybrid mononuclear organic-inorganic lanthanoid complexes is reported, based on [PW11O39]7− and 1,10-phenanthroline ligands. This hybrid approach causes a dramatic improvement of the relaxation time (×1000) with a decrease of the optimal field while maintaining the Ueff of the inorganic analogues.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-11-30 |