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RESEARCH PRODUCT
The first structurally characterized cationic lanthanide–alkyl complexesElectronic supplementary information (ESI) available: experimental and spectroscopic details. See http://www.rsc.org/suppdata/cc/b2/b201613n/
Thomas P. SpaniolJun OkudaStefan Arndtsubject
chemistry.chemical_classificationLanthanideStereochemistryRare earthMetals and AlloysCationic polymerizationGeneral ChemistryIon pairsMedicinal chemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryMaterials ChemistryCeramics and CompositesAlkyldescription
Reaction of rare earth metal–alkyl complexes [Ln(CH2SiMe3)3(THF)2] (Ln = Y, Lu) with B(C6X5)3 (X = H, F) in the presence of crown ethers gives crystallographically characterized ion pairs [Ln(CH2SiMe3)2(CE)(THF)n]+[B(CH2SiMe3)(C6X5)3]– (CE = [12]-crown-4, n = 1; CE = [15]-crown-5 and [18]-crown-6, n = 0).
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-04-02 | Chemical Communications |