6533b870fe1ef96bd12d075a
RESEARCH PRODUCT
m-Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers
Elena OleshkevichFrancesc TeixidorIsabel RomeroClara ViñasMatti HaukkaDuane Choquesillo-lazartesubject
Manganese compoundsInorganic chemistrychemistry.chemical_elementManganese010402 general chemistry01 natural sciencesInorganic ChemistryPolymer chemistrycarboranylphosphinatecoordination complexesLewis acids and basesPhysical and Theoretical Chemistryta116polymerschemistry.chemical_classificationQuímica inorgànica010405 organic chemistryLigandPolymerChemistry Inorganic0104 chemical sciencesNickelManganès -- Compostoscoordination polymerschemistrymanganesedescription
The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied Thanks to MINECO (CTQ2015-66143-P, CTQ2010-16237 and SEV-2015-0496), Generalitat de Catalunya (2014/SGR/149), and COST CM1302. E.O. who is enrolled in the PhD program of the UAB thanks for FPU grant
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-01 | Inorganic Chemistry |