6533b871fe1ef96bd12d0e1e

RESEARCH PRODUCT

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Martina EbertHelmut RingsdorfOlaf KarthausJoachim H. Wendorff

subject

Polyesterchemistry.chemical_compoundCondensation polymerMaterials sciencechemistryAzobenzeneMesogenDiscotic liquid crystalPolymer chemistrySide chainTriphenylenesense organsPendant group

description

The synthesis of a new type of combined polymers containing both disc- and rod-like mesogens is reported. The polyesters, having a triphenylene derivative as a discotic mesogen in the side group and azobenzene or biphenyl derivatives as rod-like mesogens in the main chain were characterized by polarizing microscopy, differential scanning calorimetry, and X-ray scattering studies. The homopolymer 7 is highly crystalline, while the copolymer 8 is amorphous, both, however, do not form liquid-crystalline phases.

https://doi.org/10.1002/macp.1992.021930222