6533b871fe1ef96bd12d18e4

RESEARCH PRODUCT

Gas phase heterogeneous partial oxidation reactions

Benjamín SolsonaJosé Manuel López Nieto

subject

010405 organic chemistryInorganic chemistryOxideMaleic anhydrideMolybdate010402 general chemistry01 natural sciencesRedox0104 chemical sciencesCatalysisPropenechemistry.chemical_compoundchemistryPartial oxidationAmmoxidation

description

Abstract Mixed metal oxides are used as catalysts in the gas phase partial oxidation of hydrocarbons. This paper will present the principles of catalyst choice for selective oxidation reactions as well as the structural features of metal oxide catalysts. The nature of active sites in selective oxidation reactions will also be briefly discussed. We will pay special attention to several representative reactions: (1) ODH of short chain alkanes (from C1 to C4), (2) propene partial oxidation/ammoxidation on bismuth molybdate based catalysts, (3) n-butane direct oxidation to maleic anhydride on VPO type catalysts, and (4) propane direct oxidation/ammoxidation on mixed MoVTe(Sb)Nb–O catalysts. Finally, the future trends in partial oxidation processes especially focusing on the use of biomass as a raw material will be presented.

yearjournalcountryeditionlanguage
2018-01-01
https://doi.org/10.1016/b978-0-12-811631-9.00005-3