6533b871fe1ef96bd12d1b0e

RESEARCH PRODUCT

Synthesis of a novel ditopic ligand incorporating directly bonded 1,10-phenanthroline and 2,2′:6′,2″-terpyridine units

Sergio TatayPablo Gaviña

subject

ChemistryLigandPhenanthrolineOrganic Chemistrychemistry.chemical_elementGeneral MedicineBiochemistryStille reactionchemistry.chemical_compoundDrug DiscoveryPolymer chemistryOrganic chemistryTerpyridinePalladium

description

Abstract The synthesis of a rigid ditopic ligand incorporating a 1,10-phenanthroline directly connected through its 3-position to the 5-position of a 2,2′:6′,2″-terpyridine is described. The synthesis is based on a series of palladium(0)-catalyzed cross-coupling reactions (Stille and Suzuki couplings) starting from 1,10-phenanthroline and bromo-substituted pyridines.

yearjournalcountryeditionlanguage
2006-08-22Tetrahedron Letters
https://doi.org/10.1016/j.tetlet.2006.03.025