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RESEARCH PRODUCT
Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
Eugenio CoronadoMari Carmen Giménez-lópezJoão C. WaerenborghManuel AlmeidaJosé R. Galán Mascaróssubject
chemistry.chemical_classificationInorganic chemistrySpin transitionOxalateCoordination complexInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryFerromagnetismSpin crossoverPyridineMaterials ChemistryPhysical and Theoretical ChemistryBimetallic stripMonoclinic crystal systemdescription
Abstract We present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture are filled by the spin crossover cations [Fe(bpp)2]2+ (bpp = 2,6(bispyrazol-3-yl)pyridine), free ligand and solvent molecules. No spin transition has been observed at ambient pressure.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-06-01 | Polyhedron |