6533b871fe1ef96bd12d22ec
RESEARCH PRODUCT
N-[1-(Silatran-1-yl)propyl]pentafluorobenzamide
Tanja LahtinenKari Rissanensubject
Crystallographychemistry.chemical_compoundchemistryHydrogen bondDimerAmidePentafluorobenzamideIntermolecular forceGeneral Materials ScienceGeneral ChemistryCondensed Matter Physicsdescription
In the title compound {systematic name: N-[3-(5-aza-2,8,9-trioxa-1-silabicyclo[3.3.3]undecan-1-yl)propyl]pentafluorobenzamide}, C16H19F5N2O4Si, unexpected weak anion⋯π-type C=O⋯C(aromatic) interactions form a dimer [O⋯C distances of 3.096 (3) and 3.036 (3) A]. These dimers are further connected by a normal N—H⋯O hydrogen bond [2.955 (2) A], from the amide H atom to one of the silatrane O atoms. Also, four intermolecular contacts between CH groups and silatrane O and F atoms [3.101(3)–3.406 (3) A] are observed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2007-09-21 | Acta Crystallographica Section E Structure Reports Online |