Structure and Dilution of Mesogenic Side Chains in Liquid Crystalline Polysiloxanes

6533b871fe1ef96bd12d232b

RESEARCH PRODUCT

Structure and Dilution of Mesogenic Side Chains in Liquid Crystalline Polysiloxanes

Frank Kuschel Siegmar Diele S. Oelsner Helmut Ringsdorf Bernd Hisgen

subject

Crystallography Materials science Liquid crystalline Stereochemistry Mesogen Copolymer Side chain Moiety Dilution

description

Abstract The structure of the smectic phases in four series of homo- and copolymers based on dimethylsiloxane chains with a definite variation of the concentration of the paired mesogenic side chains has been investigated by means of X-ray methods. The dilution of the mesogenic moiety was achieved by insertion of additional dimethylsiloxane segments. A nearly linear dependence of the layer spacings on the dilution has been found. A model of the structure is proposed which consists of two sublayers one of which contains the irregularly arranged main chain whereas the other one is formed by the side chains.

year	journal	country	edition	language
1988-02-01	Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics

https://doi.org/10.1080/00268948808070381

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