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RESEARCH PRODUCT
Stepwise Construction of Heterobimetallic Cages by an Extended Molecular Library Approach.
Matthias HardyFilip TopićGregor SchnakenburgNiklas StruchKari RissanenArne Lützensubject
010405 organic chemistryChemistrytrigonal-bipyramidal and cubic heterobimetallic cagesElectrospray ionizationchemistry.chemical_element010402 general chemistry01 natural sciencesCombinatorial chemistry0104 chemical sciencesIonInorganic ChemistryCrystallographyPhysical and Theoretical ChemistrySpectroscopyta116extended molecular library approachPalladiumdescription
Two novel heterobimetallic complexes, a trigonal-bipyramidal and a cubic one, have been synthesized and characterized using the same C3-symmetric metalloligand, prepared by a simple subcomponent self-assembly strategy. Adopting the molecular library approach, we chose a mononuclear, preorganized iron(II) complex as the metalloligand capable of self-assembly into a trigonal-bipyramidal or a cubic aggregate upon coordination to cis-protected C2-symmetric palladium(II) or unprotected tetravalent palladium(II) ions, respectively. The trigonal-bipyramidal complex was characterized by NMR and UV–vis spectroscopy, electrospray ionization mass spectrometry (ESI-MS), and single-crystal X-ray diffraction. The cubic structure was characterized by NMR and UV–vis spectroscopy and ESI-MS.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-12-01 | Inorganic chemistry |