6533b872fe1ef96bd12d2f20
RESEARCH PRODUCT
Isolation, dynamic NMR study and X-ray characterisation of a bis sulfonium zirconocene-ate dimer.
Philippe MeunierBruno DonnadieuEsteban OrtegaNadine Piriosubject
SulfoniumStereochemistryDimerMetals and AlloysX-rayGeneral ChemistryNuclear magnetic resonance spectroscopyCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryMaterials ChemistryCeramics and Compositesdescription
The novel dimer [Cp(2)Zr[upper bond start]([minus sign in circle])S([plus sign in circle])CH(Ph)CH[double bond]C[upper bond end]PPh(2)](2), the first example of a structurally characterised sulfur-bridged binuclear zirconathiolane complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some aspects of its solution behaviour were studied.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2004-03-11 | Chemical communications (Cambridge, England) |