6533b872fe1ef96bd12d2fb5

RESEARCH PRODUCT

Self-assembly and magnetic properties of a double-propeller octanuclear copper(II) complex with a meso-helicate-type metallacryptand core.

Yves JournauxCatalina Ruiz‐pérezXavier OttenwaelderEmilio PardoJoan CanoFrancesc LloretMiguel JulveRafael Ruiz-garcíaJorge PasánKevin Bernot

subject

Materials scienceMolecular topologyOctanuclear copperMagnetic properties ; Metallacryptand core ; Octanuclear copper ; Molecular topologyUNESCO::QUÍMICAMetals and AlloysPropeller:QUÍMICA::Química física [UNESCO]chemistry.chemical_elementNanotechnologyGeneral ChemistryCopper:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryMetallacryptand coreMagnetic propertiesMaterials ChemistryCeramics and CompositesUNESCO::QUÍMICA::Química físicaSelf-assemblyMolecular topology

description

An octanuclear copper(II) complex possessing a dimer-of-tetramers structure self-assembles from a binuclear oxamatocopper(II) metallacryptand of the meso-helicate type; its magnetic behaviour is consistent with its unique double-propeller molecular topology. Pardo Marín, Emilio José, Emilio.Pardo@uv.es ; Julve Olcina, Miguel, Miguel.Julve@uv.es ; Lloret Pastor, Francisco, Francisco.Lloret@uv.es ; Ruiz Garcia, Rafael, Rafael.Ruiz@uv.es

10.1039/b316081ehttps://pubmed.ncbi.nlm.nih.gov/15069475