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RESEARCH PRODUCT

4-Fluoroanilines: synthesis and decomposition

Borys OsmialowskiAnna ZakrzewskaErkki KolehmainenRyszard Gawinecki

subject

Inorganic ChemistryNMR spectra databasechemistry.chemical_compoundChloroformchemistryChemical shiftOrganic ChemistryEnvironmental ChemistryPhysical chemistryPhysical and Theoretical ChemistryBiochemistryDecomposition

description

Abstract Fourteen N- and/or 2-substituted 4-fluoroanilines were prepared (the series includes N–C2-bridged compounds). Some of them were found to be thermally unstable when dissolved in chloroform. Both 19 F NMR spectra and comparison of GIAO-DFT calculated and experimental 13 C chemical shifts were used to suggest decomposition products of 4-fluoroanilines.

https://doi.org/10.1016/s0022-1139(01)00401-8