6533b872fe1ef96bd12d36ce

RESEARCH PRODUCT

A novel approach to polymer-template mesoporous molecular sieves

Klaus K. UngerHans Wolfgang SpiessUlrich WiesnerAlexander Du ChesneKai SchumacherSabine RenkerRalph Ulrich

subject

chemistry.chemical_classificationMaterials scienceAlcoholPolymerMolecular sieveCatalysisAmmoniachemistry.chemical_compoundVolume (thermodynamics)chemistryChemical engineeringSpecific surface areaOrganic chemistryMesoporous material

description

A novel synthesis route was developed to produce spherical silica particles. The synthesis is based on a modified Stoeber method and the room-temperature synthesis of MCM 41S-materials applying tetraethoxysilane, alcohol, water, ammonia and homopolymers as template. The specific surface area, the specific pore volume and the average pore diameter were varied in the following ranges: 5 – 1,000 m2/g; 0.1 – 1.0 cm3/g and 2-50 nm. With respect to catalytic applications hetero-atoms e.g. Al were incorporated into the silica framework.

https://doi.org/10.1016/s0167-2991(00)80189-5