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RESEARCH PRODUCT
Catalytic activity of solvated and unsolvated lanthanide halides in Friedel–Crafts acylations
Stephanie RichardDenise Barbier-baudryJean DesmursAlain Dormondsubject
inorganic chemicalsLanthanideChemistryProcess Chemistry and Technologychemistry.chemical_elementHalideHomogeneous catalysisCatalysisCatalysisSamariumPolymer chemistryAnhydrousOrganic chemistryPhysical and Theoretical ChemistrySolubilityFriedel–Crafts reactiondescription
Abstract Anhydrous lanthanide halides — chlorides and bromides — can act as homogeneous catalysts of Friedel–Crafts acylations. The catalytic activity is related to the solubility of these anhydrous salts. More soluble THF or dioxane (Diox.) neodymium and samarium adducts are more active catalysts.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-11-01 | Journal of Molecular Catalysis A: Chemical |