6533b872fe1ef96bd12d3896

RESEARCH PRODUCT

Lattice dynamics of superconducting zirconium and hafnium nitride halides

Judith Oró-soléAmparo FuertesDaniel Beltrán-porterAndrés CantareroAna Cros

subject

ZirconiumMaterials sciencePhononScatteringchemistry.chemical_elementNitrideMolecular physicsHafniumBond lengthsymbols.namesakeLattice constantchemistrysymbolsPhysics::Atomic PhysicsRaman spectroscopy

description

We have performed a study of the Raman active modes of β-HfNCl, β-ZrNCl, and β-ZrNBr and Na-doped β-HfNCl in various scattering configurations. The experimental values are compared with a lattice dynamical calculation andassigned to definite atomic motions. The variation of the atomic force constants are analyzed as a function of the bond length, relating their relative strength with the atomic characteristics of the compound.

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