6533b872fe1ef96bd12d3c21
RESEARCH PRODUCT
Asymmetric [N–I–N]+ halonium complexes
Jas S. WardGiorgia FioriniAntonio FronteraKari Rissanensubject
kemialliset sidoksethalogeenitkompleksiyhdisteetdescription
The first asymmetric halogen-bonded iodonium complexes [I(py)(4-DMAP)]PF6 (2c) and [I(py)(4-Etpy)]PF6 (2e) were prepared via [N-Ag-N]+ → [N-I-N]+ cation exchange of their analogous 2-coordinate silver complexes. The complexes were characterised by 1H and 1H-15N HMBC NMR spectroscopy, and single crystal X-ray crystallography. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2020-01-01 |