6533b872fe1ef96bd12d4091
RESEARCH PRODUCT
Synthesis of an Acceptor–Donor–Acceptor Multichromophore Consisting of Terrylene and Perylene Diimides for Multistep Energy Transfer Studies
Thomas BaschéSebastian StappertKlaus MüllenChen Lisubject
010405 organic chemistryChemistryGeneral Chemical EngineeringEnergy transferGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesAcceptor0104 chemical scienceschemistry.chemical_compoundDiimideMaterials ChemistryMulticomponent systemsDonor acceptorPerylenedescription
Motivated by the results obtained from the investigation of singlet–singlet annihilation in a linear multichromophore comprising terrylene diimides (TDI) and perylene diimide (PDI) in 2010, we report the detailed process toward the successful synthesis of a TDI–PDI–TDI dyad. Ineffective synthetic pathways, which were necessary for the understanding of the step-by-step construction of the complex multichromophore, are described, leading toward a universal synthetic plan for multicomponent systems containing rylene diimides separated by rigid oligophenylene spacers.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-01-20 | Chemistry of Materials |