6533b872fe1ef96bd12d412e

RESEARCH PRODUCT

Isobaric vapor–liquid equilibria for binary and ternary mixtures with cyclohexane, cyclohexene, and morpholine at 100kPa

Beatriz MarrufoSonia LorasMargarita Sanchotello

subject

UNIQUACTernary numeral systemCyclohexaneGeneral Chemical EngineeringGeneral Physics and AstronomyThermodynamicschemistry.chemical_compoundchemistryAzeotropeNon-random two-liquid modelIsobaric processPhysical and Theoretical ChemistryTernary operationUNIFAC

description

Abstract Vapor–liquid equilibria (VLE) data at 100 kPa have been determinated for the ternary system cyclohexane + cyclohexene + morpholine and two constituent binary systems cyclohexane + morpholine and cyclohexene + morpholine. The thermodynamic consistency of experimental data has been verified. Both binary systems deviate moderately from ideality without the presence of an azeotrope. The VLE data have been well correlated using local composition models (Wilson, NRTL and UNIQUAC) and have been also predicted with the original UNIFAC.

yearjournalcountryeditionlanguage
2010-09-01Fluid Phase Equilibria
https://doi.org/10.1016/j.fluid.2010.04.008