Three phenanthroline-metal complexes with topologically similar but geometrically different conformations.

6533b872fe1ef96bd12d432b

RESEARCH PRODUCT

Three phenanthroline-metal complexes with topologically similar but geometrically different conformations.

Ricardo Baggio Miguel Angel Harvey Sebastian Suarez

subject

crystal structure Stereochemistry Phenanthroline chemistry.chemical_element Zinc Crystal structure Química Inorgánica y Nuclear 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences strong C—H⋯O intramolecular hydrogen bonds CRYSTAL STRUCTURE Research Communications lcsh:Chemistry Metal Base (group theory)//purl.org/becyt/ford/1 [https]chemistry.chemical_compound Group (periodic table)strong C—H...O intramolecular hydrogen bonds Cd and Zn complexes PEROXODISULFATE ANION //purl.org/becyt/ford/1.4 [https]General Materials Science STRONG C - H⋯O INTRAMOLECULAR HYDROGEN BONDS Cadmium Hydrogen bond Ciencias Químicas General Chemistry Condensed Matter Physics peroxodisulfate anion 0104 chemical sciences Crystallography lcsh:QD1-999 chemistry visual_art visual_art.visual_art_medium peroxodisulfate anion CD AND ZN COMPLEXES CIENCIAS NATURALES Y EXACTAS

description

Two out of the three very similar complexes described present twofold symmetry but not the third one, probably by way of a strong intramolecular C—H⋯O hydrogen bond disrupting the symmetry, a fact which is analysed in detail.

year	journal	country	edition	language
2016-11-01	Acta crystallographica. Section E, Crystallographic communications

10.1107/s2056989016016029 https://pubmed.ncbi.nlm.nih.gov/27840713

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