ChemInform Abstract: Novel Unsymmetrical ortho-Metalated Dirhodium(II) Catalysts: trans Influence of the Axial Ligand.

6533b873fe1ef96bd12d4abf

RESEARCH PRODUCT

ChemInform Abstract: Novel Unsymmetrical ortho-Metalated Dirhodium(II) Catalysts: trans Influence of the Axial Ligand.

M. Angeles Ubeda Pascual Lahuerta Julia Pérez-prieto Salah‐e. Stiriba

subject

Stereochemistry Chemistry Group (periodic table)Ligand Trans effect Reactivity (chemistry)General Medicine Medicinal chemistry Catalysis

description

Inductive effects of an X axial group which are transmitted through the RhRh bond influence the reactivity of ortho-metalated dirhodium complexes 3 in the cyclization of 1-diazo-5-penten-2-one (4).

year	journal	country	edition	language
2010-06-15	ChemInform

https://doi.org/10.1002/chin.199920025

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