6533b873fe1ef96bd12d4b5c

RESEARCH PRODUCT

Mid gap photoluminescence from GaN:Mn, a magnetic semiconductor

H. MedinaOliver AmbacherAndrés CantareroN.v. Joshi

subject

PhotoluminescenceMaterials scienceBand gapExcited stateAnalytical chemistryGeneral Materials ScienceGeneral ChemistryMagnetic semiconductorEmission spectrumCondensed Matter PhysicsSpectroscopyFluorescenceLine (formation)

description

Abstract The defect and morphology of GaN monocrystals with Mn content 10 19  cm −3 were examined by fluorescence confocal microscopy and spectroscopy. The fluorescence spectral investigation was carried out in a region very close to the defect centers. Contrary to earlier results, we did observe a characteristic fluorescence line of Mn corresponding to the 4 T 1 → 6 A 1 and 4 T 2 → 6 A 1 transitions, suggesting the predominant presence of Mn 2+ (d 5 ). In addition, strong emission lines were observed at 1.60 and at 1.85 eV when the sample was excited with light of 436 and 365 nm, respectively. An energy scheme is proposed to explain the observed data coherently.

https://doi.org/10.1016/s0022-3697(03)00070-2