6533b873fe1ef96bd12d4ee8

RESEARCH PRODUCT

Cation-translocation based isomerism offers a tool for the expansion of compressed helicates.

Christian MevissenDavid SommerKhai-nghi TruongKari RissanenSabarina VasanthakumarMarkus Albrecht

subject

Inorganic ChemistryCrystallographylawChemistryCrystallizationlaw.invention

description

A series of compressed M[Li313Ti2] (M = Li, Na, K, Rb, Cs) and expanded helicates M4[13Ti2] has been obtained. The helicates Li3[M13Ti2] or M4[13Ti2] with M = Na+, K+, Rb+, or Cs+ adopt the expanded structure in solution. By crystallization the compressed structures M[Li313Ti2] (M = Na, Rb) are obtained. This represents an example of cation-translocation based isomerism.

yearjournalcountryeditionlanguage
2021-06-15Dalton transactions (Cambridge, England : 2003)
10.1039/d1dt01707ahttps://pubmed.ncbi.nlm.nih.gov/34124723