6533b873fe1ef96bd12d584c

RESEARCH PRODUCT

Anomalous diffraction profiles of alkali-halide-alkali-cyanide mixed crystals.

K. KnorrAlois Loidl

subject

chemistry.chemical_classificationDiffractionMaterials sciencechemistryX-ray crystallographyCenter (category theory)Analytical chemistryGeneral Physics and AstronomyWave vectorAlkali metalInorganic compoundIntensity (heat transfer)Solid solution

description

The x-ray diffraction profiles of four mixed alkali halides-alkali cyanides have been studied. At the threshold concentration where the systems change over from ferroelastic ordering to the glass state, the profiles are highly unusual. The diffracted intensity of transverse scans along the cubic axes follows $I\ensuremath{\sim}\mathrm{exp}(\ensuremath{-}\ensuremath{\alpha}|\ensuremath{\xi}|)$, where $\ensuremath{\xi}$ is the reduced wave vector, measured from the line center.

10.1103/physrevlett.57.460https://pubmed.ncbi.nlm.nih.gov/10034065