6533b873fe1ef96bd12d59e5

RESEARCH PRODUCT

Polymorphism and the glasslike state of cyanide mixed crystals: A mesoscopic problem.

K. Knorr

subject

Phase transitionchemistry.chemical_compoundMesoscopic physicsMaterials sciencechemistryPolymorphism (materials science)Condensed matter physicsChemical physicsMartensiteCyanideHalideAlkali metalSolid solution

description

The martensitic aspect of the structural phase transitions of the alkali cyanides and their solid solutions with the alkali halides is discussed. It is suggested that the polymorphism is intimately connected with the problem of mesoscopic transformation strains. At intermediate CN concentrations a competition between glasslike inhomogeneous strains, modulated strains, and ferroelastic strains is observed.

10.1103/physrevb.41.3158https://pubmed.ncbi.nlm.nih.gov/9994093