6533b874fe1ef96bd12d6047

RESEARCH PRODUCT

Synthesis of diorganotin(IV) complexes with nucleosides and their Characterization by Mössbauer and infrared spectroscopy

Giuseppe RuisiM.t. Lo GiudiceLorenzo Pellerito

subject

InfraredInorganic chemistryGuanosineInfrared spectroscopyCytidineUridineInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryMössbauer spectroscopyMaterials ChemistrymedicinePhysical and Theoretical ChemistryInosineNucleosidemedicine.drug

description

Abstract A number of new complexes of R 2 Sn IV with adenosine, guanosine, inosine, cytidine and uridine were synthesized by reaction of ribonucleosides with diorganotin oxide in hot methanol. The complexes were characterized by infrared and 119 Sn Mossbauer spectroscopy as O(2′), O(3′) (diorganostannylene) nucleosides; the occurence of dimers with three-co-ordinate oxygen atoms is inferred on the basis of spectroscopic data.

https://doi.org/10.1016/s0020-1693(00)88157-8