Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC Complexes for the Investigation of Electronic Unsymmetry by NMR

6533b874fe1ef96bd12d60cc

RESEARCH PRODUCT

Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC Complexes for the Investigation of Electronic Unsymmetry by NMR

Anthony J. Arduengo Jens Emsermann Till Opatz

subject

chemistry.chemical_classification Metal Aldimine chemistry visual_art Organic Chemistry Polymer chemistry visual_art.visual_art_medium Spectroscopy Ring (chemistry)Photochemistry Catalysis

description

Complexes of unsymmetrically substituted N-heterocyclic carbenes with NMR-active metals (Ag, Hg, Pt) with or without a 13C-label in the 2-position were synthesized by aldimine cross coupling and analyzed with respect to the scalar couplings between the metal center or C2 and the other ring atoms.

year	journal	country	edition	language
2013-07-09	Synthesis

https://doi.org/10.1055/s-0033-1338496

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6533b874fe1ef96bd12d60cc

RESEARCH PRODUCT

Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC ­Complexes for the Investigation of Electronic Unsymmetry by NMR

subject

description

Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC Complexes for the Investigation of Electronic Unsymmetry by NMR