Initial Radical Cation Pathway in the Mo2Cl10-Mediated Dehydrogenative Arene Coupling

6533b874fe1ef96bd12d63da

RESEARCH PRODUCT

Initial Radical Cation Pathway in the Mo2Cl10-Mediated Dehydrogenative Arene Coupling

Jana Leppin Katja Heinze Siegfried R. Waldvogel Moritz Schubert

subject

Chemistry Organic Chemistry chemistry.chemical_element General Chemistry Inner sphere electron transfer Photochemistry Catalysis law.invention Coupling (electronics)Electron transfer C c coupling Radical ion law Molybdenum Electron paramagnetic resonance

description

Experimental (EPR) and theoretical (DFT) evidence is provided for radical cation formation as initial step in the Mo2Cl10-mediated dehydrogenative arene coupling. The initial electron transfer from methoxyarenes to molybdenum proceeds via an inner sphere mechanism.

year	journal	country	edition	language
2015-01-28	Chemistry - A European Journal

https://doi.org/10.1002/chem.201406522

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