Search results for " Active"
showing 10 items of 533 documents
Theoretical studies on the spectroscopy of the 7-azaindole monomer and dimer
2001
The absorption and the emission spectra, both fluorescence and phosphorescence, of the 7-azaindole molecule have been studied by means of the complete active space (CAS) SCF method and multiconfigurational second-order perturbation theory (CASPT2). Excitation energies, oscillator strengths, dipole moments, transition dipole moments, and their directions have been computed and the results compared to those of analogous molecules such as indene, indole, and benzimidazole, to get a homogeneous picture of the photophysics of the systems. The absorption and emission of the 7-azaindole dimer and its related tautomer have also been computed in order to get further insight into the double fluoresce…
A Theoretical Study of the Electronic Spectra of N9 and N7 Purine Tautomers
1999
The complete active space (CAS) SCF method and multiconfigurational second-order perturbation theory (CASPT2) have been used to study electronic spectra of the N(9)H and N(7)H tautomers of purine. The calculations include vertical excitation energies, oscillator strengths, dipole moments, and transition moment directions in gas phase. In accord with experiment in nonpolar solvents, the two lowest π → π* excited singlet valence states are predicted to be located at 4.7 and 5.1 eV. The latter is expected to shift to the red in aqueous solutions. A satisfactory interpretation of the electronic spectra above 5.5 eV is obtained if the experimental data are assumed to consist of the superposition…
Polymer-based systems for controlled release and targeting of drugs
2019
The current need to find new advanced approaches to carry biologically active substances (conventional organic drugs, peptides, proteins (such as antibodies), and nucleic acid-based drugs (NABDs such as siRNA and miRNA)) in the body fluids, to realize targeted therapies and even personalized ones, goes hand in hand with research on the performance of new materials to better realize appropriate drug vectors [...]
Situated Language Learning Methods: a cross-sectional study on General Teaching and Language teaching
2018
Language teaching bases its theoretical and methodological framework on an axiom: object and teaching tool coincide in the target language. There follows that active learning is the key to efficacious linguistic knowledge as well as to transferable learning from a specific disciplinary context to a general one. This perspective is in tune with the educational claims and the learning aims fixed by the EAS teaching model, according to which learning is mediated by action and by the learner’s ability to simulate real life situations within classroom The present study means to start up an epistemological reflection moving from the comparison between language teaching and general teaching with r…
Evaluation of the LSA-SAF gross primary production product derived from SEVIRI/MSG data (MGPP)
2020
The objective of this study is to describe a completely new 10-day gross primary production (GPP) product (MGPP LSA-411) based on data from the geostationary SEVIRI/MSG satellite within the LSA SAF (Land Surface Analysis SAF) as part of the SAF (Satellite Application Facility) network of EUMETSAT. The methodology relies on the Monteith approach. It considers that GPP is proportional to the absorbed photosynthetically active radiation APAR and the proportionality factor is known as the light use efficiency ε. A parameterization of this factor is proposed as the product of a εmax, corresponding to the canopy functioning under optimal conditions, and a coefficient quantifying the reduction of …
Surface soil humidity retrieval by means of a semi-empirical coupled SAR model
2010
In the last years, the availability of new technologies of Earth Observation encouraged researches to use integrated approaches for environmental monitoring. Even for agro-hydrological applications, remotely sensed data are available on wide areas allowing the retrieval of cost-effective and representative estimation of high spatial and temporal variability of the soil-vegetation system variables. In particular, soil water content plays an important role determining the partition of precipitation between surface runoff and infiltration and, moreover, influences the distribution of the incoming radiation between latent and sensible heat flux. As a consequence, distributed soil water content …
Drought Monitoring In The Mediterranean Basin Using The Seviri/Msg Gpp Product (Mgpp)
2020
Recently, the Satellite Application Facility for Land Surface Analysis (LSA-SAF) has just released a new product that helps to characterize ecosystem processes, the 10-day LSA SAF GPP product from SEVIRI/MSG data (MGPP LSA-411). The GPP product is based on Monteith's concept, which models GPP as the product of the incoming photosynthetically active radiation (PAR), the fractional absorption of that flux $(\mathrm{f}_{APAR})$ and a light-use efficiency factor $(\varepsilon)$. Preliminary results on the use of the MGPP product in the assessment of ecosystem response to drought events are presented in this work for a short period of three years. A few sites located in the Mediterranean basin a…
L'influence de la formation initiale sur les modalités d'insertion dans la vie active
1977
référence interne : 77021
Most of the field/inductive substituent effect works through the bonds
2019
AbstractAn application of the quantum chemical modeling allowed to investigate the nature of the field/inductive substituent effect (SE). For this purpose, series of X-tert-butyl···tert-butane (TTX) complexes (where X = NMe2, NH2, OH, OMe, Me, H, F, Cl, CF3, CN, CHO, COMe, CONH2, COOH, NO2, NO) were studied. A starting distance between central carbon atoms in substituted and unsubstituted fragments of TTX, dC1–C4, was the same as the distance C1–C4 in X-substituted bicyclo[2.2.2]octane (BCO), where the SE acts both via bonds and via space. A strength of interaction between substituted and unsubstituted components of TTX was described by deformation and interaction energies. The substituent …
Modeling transpiration and leaf temperature of urban trees – A case study evaluating the microclimate model ENVI-met against measurement data
2018
Abstract Increasing vegetation cover in cities is a key approach to mitigating urban heat excess. However, both the effect of vegetation on microclimate and the plants’ vitality need to be assessed to support and quantify the effects of such strategies. One way to assess the interactions between vegetation and the urban environment is through microclimate models that can simulate the effects of vegetation onto the urban microclimate as well as effects of urban environments onto vegetation. To provide reliable estimates microclimate models need to be parameterized based on empirically obtained data. In this paper we compare modeled transpiration rates and leaf temperatures of a leading micro…