Search results for " Analytic"

showing 10 items of 1718 documents

Non-contact breath sampling for sensor-based breath analysis

2019

Breath analysis holds great promise for real-time and non-invasive medical diagnosis. Thus, there is a considerable need for simple-in-use and portable analyzers for rapid detection of breath indicators for different diseases in their early stages. Sensor technology meets all of these demands. However, miniaturized breath analyzers require adequate breath sampling methods. In this context, we propose non-contact sampling; namely the collection of breath samples by exhalation from a distance into a miniaturized collector without bringing the mouth into direct contact with the analyzing device. To evaluate this approach different breathing maneuvers have been tested in a real-time regime on a…

AdultMalePulmonary and Respiratory MedicineSpectrum analyzer:MEDICINE [Research Subject Categories]breath samplingDiaphragmatic breathingContext (language use)01 natural sciencesYoung Adult03 medical and health sciences0302 clinical medicinevolatile organic compoundsHumansbreath analysisVolatile Organic CompoundsRespiration010401 analytical chemistryBreath samplingExhalationSampling (statistics)Middle AgedPTR-MS0104 chemical sciencesBreath Tests030228 respiratory systemBreath gas analysisBreathingEnvironmental scienceFemaleBiomedical engineeringJournal of Breath Research
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In vivo sodium release and saltiness perception in solid lipoprotein matrices. 2. Impact of oral parameters

2012

This study aimed to investigate the relationships between sodium release, saltiness, and oral parameters during the eating of lipoprotein matrices (LPM). Sodium release and saltiness relative to 10 LPM were recorded during normal mastication by five subjects with differing oral parameters (chewing efficiency and salivary flow rate). The LPM samples varied in composition (dry matter, fat, salt, and pH levels) and represented a broad range of hardness. Mastication was recorded using electromyography simultaneously with sensory assessment. Differences in chewing behavior could explain most of the variability in sodium release and saltiness among subjects. Subjects with a higher chewing force a…

AdultMaleSodiumLipoproteins[ SDV.AEN ] Life Sciences [q-bio]/Food and Nutritionchemistry.chemical_element01 natural sciencesYoung Adult0404 agricultural biotechnologyIn vivoFood and NutritionHumansDry matterFood scienceSodium Chloride DietaryMasticationMouthChemistry010401 analytical chemistrydigestive oral and skin physiologyTaste Perception04 agricultural and veterinary sciencesGeneral ChemistryMiddle AgedSalivary flow rate040401 food science0104 chemical sciencesstomatognathic diseasesAlimentation et NutritionMasticationFemaleGeneral Agricultural and Biological Sciences[SDV.AEN]Life Sciences [q-bio]/Food and NutritionLipoprotein
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Case report: Another death associated to γ-hydroxybutyric acid intoxication

2019

Abstract We report a fatal γ-hydroxybutyric acid (GHB) intoxication of a forty-year old man. According to an acquaintances’ statement, the deceased had drunk a beverage containing GHB approximately five hours before he was found. Postmortem GHB concentrations were determined using gas chromatography coupled to single quadrupole mass spectrometry after simple protein precipitation with methanol and derivatization with BSTFA (1% TMCS). Concentrations in body fluids and tissues of the deceased were as follows: cardiac blood 384 mg/L, femoral blood 358 mg/L, urine 864 mg/L, brain tissue 211 mg/kg, liver tissue 201 mg/kg, kidney tissue 492 mg/kg, bile 334 mg/L and gastric content 2025 mg/L. In a…

AdultMaleSubstance-Related DisordersPlastic bottleHydroxybutyratesUrineKidneyMass spectrometry01 natural sciencesGas Chromatography-Mass SpectrometryPathology and Forensic MedicineBeveragesboatsForensic Toxicology03 medical and health scienceschemistry.chemical_compound0302 clinical medicinemedicineBileHumansProtein precipitation030216 legal & forensic medicineDerivatizationBrain ChemistryKidneyChromatographyChemistry010401 analytical chemistryBSTFAboats.hull_materialGastrointestinal Contents0104 chemical sciencesmedicine.anatomical_structureLiverGas chromatographyLawChromatography LiquidHairForensic Science International
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The synthetic cannabinoid 5F-MDMB-PICA: A case series

2020

5F-MDMB-PICA has been detected in products sold on the internet as well as in biological samples since 2016. It is associated with serious adverse health and behavioral effects and even death. Herein we report on twelve cases with proven 5F-MDMB-PICA consumption, including three fatalities, four cases of driving under the influence of drugs and five other criminal acts. In these cases, 5F-MDMB-PICA was detected in postmortem blood or serum. Concentrations ranged from 0.1-16ng/mL. In some blood (serum) and urine samples, the hydrolysis metabolite of 5F-MDMB-PICA (M12) could also be detected. In this case series, co-consumption with other drugs occurred in 9 of 12 cases, most commonly alcohol…

AdultMaleSubstance-Related Disordersmedicine.medical_treatmentPhysiology01 natural sciencesMass SpectrometryPathology and Forensic Medicine03 medical and health sciences0302 clinical medicineLimit of DetectionPupil DisordersSynthetic cannabinoidsmedicineHumans030216 legal & forensic medicinePica (disorder)ConfusionAdverse effectDriving Under the InfluencePostural BalanceDriving under the influenceSlurred speechMolecular StructurebiologyCannabinoidsIllicit DrugsMood Disordersbusiness.industrySolid Phase Extraction010401 analytical chemistrycelebritiesPostmortem bloodMiddle Agedbiology.organism_classification0104 chemical sciencesAggressioncelebrities.reason_for_arrestSensation DisordersFemaleCrimeCannabinoidCannabismedicine.symptombusinessConjunctivaLawChromatography Liquidmedicine.drugForensic Science International
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Detection of γ‐hydroxybutyric acid‐related acids in blood plasma and urine: Extending the detection window of an exogenous γ‐hydroxybutyric acid inta…

2021

In crimes facilitated by γ-hydroxybutyric acid (GHB) administration, the frequent occurrence of anterograde amnesia of the victims as well as the short detection window and variations of endogenous GHB concentrations complicate obtaining analytical proof of GHB administration. Because elevated endogenous organic acid concentrations have been found in the urine of patients with succinic semialdehyde deficiency (leading to accumulation of GHB in human specimens) and after GHB ingestion, we searched for an alternative way to prove GHB administration via detection of elevated organic acid concentrations in blood plasma and urine. We collected blood and urine samples from narcolepsy patients (n …

AdultMalemedicine.medical_specialtyAdolescentHydroxybutyratesPharmaceutical ScienceEndogenyUrine01 natural sciencesGas Chromatography-Mass SpectrometryAnalytical ChemistrySuccinic semialdehyde03 medical and health scienceschemistry.chemical_compound0302 clinical medicineInternal medicineBlood plasmamedicineHumansEnvironmental ChemistryIngestion030216 legal & forensic medicineSpectroscopyGlycolic acidAgedNarcolepsychemistry.chemical_classificationCreatinineChemistry010401 analytical chemistryMiddle Aged0104 chemical sciencesSubstance Abuse DetectionEndocrinologyFemaleOrganic acidDrug Testing and Analysis
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Levels of GHB in hair after regular application.

2021

Gamma hydroxybutyrate (GHB) is a central nervous system depressant that is an approved drug for the treatment of narcolepsy with cataplexy and other syndromes. Due to its dose dependent stimulating, relaxing or sedative effects, illicit abuses include recreational use by young people and cases of drug-facilitated crime (DFC). Since GHB is also produced endogenously, for forensic questions, it is important to be able to differentiate between endogenous GHB and elevated levels due to additional intake. In this study, we measured GHB concentrations in hair of patients with narcolepsy receiving daily GHB treatment. The results were compared to endogenous concentrations and concentrations after …

AdultMalemedicine.medical_specialtyAdolescentSodium OxybateDose dependenceRecreational use01 natural sciencesPathology and Forensic Medicine03 medical and health sciencesYoung Adult0302 clinical medicineTandem Mass SpectrometryInternal medicineMedicineHumans030216 legal & forensic medicineNarcolepsySleep disorderbusiness.industry010401 analytical chemistryCentral Nervous System DepressantsGamma hydroxybutyratemedicine.disease0104 chemical sciencesSodium saltEndocrinologySedative EffectsFemalebusinessSodium OxybateLawNarcolepsyChromatography LiquidHairForensic science international
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Biomonitoring of Multiple Mycotoxins in Urine by GC–MS/MS: A Pilot Study on Patients with Esophageal Cancer in Golestan Province, Northeastern Iran

2021

A pilot study to investigate the occurrence of 10 mycotoxins (deoxynivalenol, DON

AdultMalemedicine.medical_specialtyEsophageal NeoplasmsLiquid Phase MicroextractionHealth Toxicology and Mutagenesislcsh:MedicinePilot ProjectsUrineIranToxicologymedicine.disease_cause01 natural sciencesGastroenterologyDiacetoxyscirpenolGas Chromatography-Mass SpectrometryArticlechemistry.chemical_compoundYoung Adult0404 agricultural biotechnologyInternal medicinemycotoxinsmedicineHumansZearalanoneesophageal cancerMycotoxinZearalenoneAgedAged 80 and overCreatininebusiness.industryToxin010401 analytical chemistrylcsh:RGC–MS/MSurine biomarkers04 agricultural and veterinary sciencesMiddle Aged040401 food science0104 chemical scienceschemistryCase-Control StudiesBody BurdenFemaleGas chromatography–mass spectrometrybusinessBiological MonitoringToxins
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Hanging disguised as bondage: accidental or suicidal death?

2020

The concept of autoerotic asphyxiation refers to the use of devices or substances intended to enhance one's arousal by inducing cerebral hypoxia, which can involuntarily lead to death. Although in most cases death occurs accidentally, it is nonetheless true that the same devices might be used by the practitioners in order to attempt suicide. The case of a 34-year-old practitioner of autoerotic asphyxiation found dead in his apartment with bondage-like ligatures and masking is reported here. The case raised some issues concerning the accidental or suicidal nature of the act. The aspects taken into account in the management of the case are discussed, along with a compared approach to the data…

AdultMalemedicine.medical_specialtyInjury controlBondagePoison control01 natural sciencesSuicide preventionOccupational safety and healthPathology and Forensic MedicineNeck InjuriesAsphyxia03 medical and health sciencesFatal Outcome0302 clinical medicineSettore MED/43 - Medicina LegaleInjury preventionmedicineHumans030216 legal & forensic medicineHypoxiaPsychiatryParaphilic Disorders010401 analytical chemistryHyoid BoneHuman factors and ergonomicsAutoerotic asphyxiationGeneral Medicine0104 chemical sciencesHangingAccidents HomeAccidentalAutoerotic deathBlood Alcohol ContentPsychologyAttempt suicideForensic Science, Medicine and Pathology
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Human infant saliva peptidome is modified with age and diet transition.

2012

Abstract In order to describe developmental changes in human salivary peptidome, whole saliva was obtained from 98 infants followed longitudinally at 3 and 6 months of age. Data on teeth eruption and diet at the age of 6 months were also recorded. Salivary peptide extracts were characterised by label-free MALDI-MS. Peptides differentially expressed between the two ages, and those significantly affected by teeth eruption or introduction of solid foods were identified by MALDI TOF–TOF and LC ESI MS–MS. Out of 81 peaks retained for statistical analysis, 26 were overexpressed at the age of 6 months. Exposure to solid foods had a more pronounced effect on profiles (overexpression of nine peaks) …

AdultMalemedicine.medical_specialtySalivaAgingProteomeBiophysicsBiology01 natural sciencesBiochemistryTooth Eruption03 medical and health sciencesstomatognathic systemInternal medicinemedicineHumansStatistical analysisWhole salivaSalivary Proteins and PeptidesSalivaComputingMilieux_MISCELLANEOUS030304 developmental biology0303 health sciencesChromatographyTransition (genetics)010401 analytical chemistryInfantFeeding Behavior0104 chemical sciencesEndocrinologySolid foodHistatinSalivary ProteinsFemalePeptides[SDV.AEN]Life Sciences [q-bio]/Food and NutritionJournal of proteomics
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Diagnosis and Classification of 17 Diseases from 1404 Subjects via Pattern Analysis of Exhaled Molecules.

2016

We report on an artificially intelligent nanoarray based on molecularly modified gold nanoparticles and a random network of single-walled carbon nanotubes for noninvasive diagnosis and classification of a number of diseases from exhaled breath. The performance of this artificially intelligent nanoarray was clinically assessed on breath samples collected from 1404 subjects having one of 17 different disease conditions included in the study or having no evidence of any disease (healthy controls). Blind experiments showed that 86% accuracy could be achieved with the artificially intelligent nanoarray, allowing both detection and discrimination between the different disease conditions examined.…

AdultMalevolatile organic compounddiagnosisGeneral Physics and AstronomyPattern analysisMetal NanoparticlesNanotechnology02 engineering and technologyBiosensing Techniques01 natural sciencesArticlePattern Recognition AutomatedArtificial IntelligencesensornoninvasiveMedicineHumansGeneral Materials Sciencecarbon nanotubeVolatile Organic Compoundsdiseasebreathbusiness.industryNanotubes Carbonnanoparticle010401 analytical chemistryGeneral EngineeringPattern recognitionMiddle Aged021001 nanoscience & nanotechnology0104 chemical sciences3. Good healthBreath TestsCase-Control StudiesFemaleArtificial intelligenceGold0210 nano-technologybusinessACS nano
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