Search results for " Assisted"

showing 10 items of 241 documents

Co(II)-mediated synthesis of 2-carbamimidoylbenzoates and isoindole-1,3-diaminates

2015

Abstract Phthalonitrile, acetoxime and cobalt(II) nitrate hexahydrate are combined in acetone with formation of stable and easy to handle Co(II) complex [Co{C6H4C(NH2)NC(ONCMe2)2}2](NO3)2 (1). Interaction of 1 with excess alcohols ROH (also used as solvents) and 2 equiv of (NH4)2S leads, in one-step, to alkyl 2-carbamimidoylbenzoate nitrates [C6H4COOR{2-C(NH2)2}]NO3 [R=CH3, C2H5, C3H7, CH(CH3)2]. Similarly, N1,N3-dialkyl-1H-isoindole-1,3-diaminate nitrates [C6H4C(NR′)NC(NR′)]NO3 [R=C3H7, C4H9, C(CH3)3, CH2CH2OH, CH2CH2SC2H5) can be directly produced from 1 by its reaction with 4 equiv of amines and 2 equiv of (NH4)2S in alcoholic media.

chemistry.chemical_classificationphthalonitrilesChemistryStereochemistrymetal assisted (mediated) synthesisOrganic Chemistrychemistry.chemical_elementN1oximesBiochemistryMedicinal chemistryPhthalonitrilechemistry.chemical_compoundNitrateDrug DiscoveryAcetone3-diaminatesIsoindoleCobaltta116alkyl 2-carbamimidoylbenzoatesN3-dialkyl-isoindole-1AlkylTetrahedron
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Synthesis of Carbolines via Microwave-Assisted Cadogan Reactions of Aryl-Nitropyridines

2018

chemistry.chemical_compoundchemistryMicrowave chemistry010405 organic chemistryArylPhosphoruschemistry.chemical_elementOrganic chemistryGeneral Chemistry010402 general chemistry01 natural sciencesMicrowave assisted0104 chemical sciencesChemistrySelect
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Development and Design of Reactors in Microwave‐Assisted Chemistry

2012

chemistry.chemical_compoundchemistryOrganic chemistryOrganic synthesisNanotechnologyMicrowave assistedCatalysisMicrowaves in Organic Synthesis
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Ultrasound assisted reductive cleavage of sesquiterpene γ-enonelactones

1995

Abstract Ultrasound enhances the rate of reductive cleavage of the C 6 -oxygen bond of several cis - and trans - sesquiterpene γ-enonelactones. Interestingly ultrasound overrides the stereoelectronic requirements for the reductive cleavage of the most usually occurring sesquiterpene trans -lactones.

chemistry.chemical_compoundchemistryStereochemistryReductive cleavageOrganic ChemistryDrug DiscoveryOrganic chemistrychemistry.chemical_elementSesquiterpeneUltrasound assistedBiochemistryOxygenTetrahedron Letters
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Crystal structure and Hirshfeld surface analysis of (E)-3-[(4-fluorobenzylidene)amino]-5-phenylthiazolidin-2-iminium bromide

2019

TARAMAPUBMED TARAMASCOPUS TARAMAWOS In the cation of the title salt, C16H15FN3S+·Br−, the phenyl ring is disordered over two sets of sites with a refined occupancy ratio of 0.503 (4):0.497 (4). The mean plane of the thia­zolidine ring makes dihedral angles of 13.51 (14), 48.6 (3) and 76.5 (3)° with the fluoro­phenyl ring and the major- and minor-disorder components of the phenyl ring, respectively. The central thia­zolidine ring adopts an envelope conformation. In the crystal, centrosymmetrically related cations and anions are linked into dimeric units via N—H...Br hydrogen bonds, which are further connected by weak C—H...Br hydrogen bonds into chains parallel to [110]. Hirshfeld surface an…

crystal structureStackingCrystal structure010402 general chemistryRing (chemistry)01 natural sciencesCrystalHirshfeld surface analysis.chemistry.chemical_compoundBromideThia­zolidine ringcharge assisted hydrogen bondingHirshfeld surface analysisGeneral Materials ScienceBenzeneCrystallography010405 organic chemistryHydrogen bondIminiumdisorderGeneral ChemistryCondensed Matter::Mesoscopic Systems and Quantum Hall EffectCondensed Matter Physics0104 chemical sciencesCrystallographychemistryQD901-999thiazolidine ringActa Crystallographica Section E Crystallographic Communications
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A deterministic simulation study of embryo marker-assisted selection for age at first calving in Nellore (Bos indicus) beef cattle

2007

Submitted by Guilherme Lemeszenski (guilherme@nead.unesp.br) on 2013-08-22T19:04:58Z No. of bitstreams: 1 S1415-47572007000400008.pdf: 85300 bytes, checksum: 7422029b120457123fb366c1bd71e758 (MD5) Made available in DSpace on 2013-08-22T19:04:58Z (GMT). No. of bitstreams: 1 S1415-47572007000400008.pdf: 85300 bytes, checksum: 7422029b120457123fb366c1bd71e758 (MD5) Previous issue date: 2007-01-01 Made available in DSpace on 2013-09-30T20:08:32Z (GMT). No. of bitstreams: 2 S1415-47572007000400008.pdf: 85300 bytes, checksum: 7422029b120457123fb366c1bd71e758 (MD5) S1415-47572007000400008.pdf.txt: 39461 bytes, checksum: 2796161439379a834535eeaff8aac2ba (MD5) Previous issue date: 2007-01-01 Submitt…

dairy-cattlelcsh:QH426-470Ice calvingefficient productionBeef cattleBiologyAnimal Breeding and Genomicsbreeding schemesmarker-assisted selectionmultistage selectionoutbred populationage at first calvingMarker assisted selectionAnimal sciencebeef cattleGenetic variationGeneticsFokkerij en GenomicaMolecular BiologySelection (genetic algorithm)Dairy cattlereproductive traitsbusiness.industryfungibovine preimplantation embryosfood and beveragesBeef cattlegenetic-linkage mapMarker-assisted selectionrespiratory systemBiotechnologyTransplantationlcsh:Geneticspre-selectionGenetic gainsingle blastomerequantitative trait lociWIASbusiness
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Minimally Invasive Video-Assisted Thyroidectomy: Analysis of Complications From a Systematic Review

2019

Background. Nowadays, minimally invasive video-assisted thyroidectomy (MIVAT) is considered a safe and effective option. However, its complication rate has not been specifically discussed yet. The aim of this systematic review was enrolling a large number of studies to estimate early and late complications (transient and definitive, uni- and bilateral laryngeal nerve palsy; transient and definitive hypocalcemia; cervical hematoma; hypertrophic or keloid scar) of MIVAT compared with conventional technique. Methods. The review was performed according to PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) criteria in PubMed and Embase. Search terms were “minimally inva…

definitive complicationmedicine.medical_specialtybusiness.industrytransient complicationsmedicine.medical_treatmentreviewThyroidectomyVideo-Assisted SurgeryMIVATSurgery03 medical and health sciencesVideo assisted thyroidectomyPostoperative Complications0302 clinical medicineminimally invasive video-assisted thyroidectomy030220 oncology & carcinogenesisThyroidectomyHumansMinimally Invasive Surgical ProceduresMedicine030211 gastroenterology & hepatologySurgeryComplication ratebusinessconventional thyroidectomySurgical Innovation
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Educational change : a case study of the implementation of the national information strategy

1997

educational changeforeign language teachingpolicy implementationcomputer assisted language learning
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Can cycling with an E-bike improve fitness? : effect of access to an Electric Assisted Bicycle on cycling distance and cardiopulmonary fitness in ina…

2016

Masteroppgave folkehelsevitenskap - Universitetet i Agder 2016 Background: The aims of the present study were to assess the effect of an eight-month intervention with access to an Electric assisted bicycle (E-bike) on (1) the amount of E-biking, (2) changes in cardiopulmonary fitness and (3) to assess whether cycled distance was associated with changes in cardiopulmonary fitness, among inactive adults. Methods: Twenty-five inactive Norwegian adults (33 – 57 years of age, 72 % women), were recruited through convenience sampling. Participants were given an E-bike for eight (N = 23) or three (N = 2) months. Socio-demographic characteristics were reported with a questionnaire. Bicycle use was m…

electric assisted bicycleME516active commutingGPSmaximal oxygen uptakecycling distancemaksimalt oksygenopptakaktiv transportelektrisk sykkelVDP::Medical disciplines: 700::Health sciences: 800human activitiessyklet distanse
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Standardization of sampling and staining methods for the morphometric evaluation of sperm heads in the Cynomolgus monkey (Macaca fascicularis) using …

2005

Automated sperm morphology analysis (ASMA) technology has improved the assessment of sperm morphology, but the results depend on the use of adequate and standardized procedures. In this study the Sperm-Class Analyzer® (SCA) ASMA system was used to assess sperm head morphometry in the Cynomolgus monkey and to evaluate the influence of sample size, intraslide variation, and the use of three staining techniques on the accuracy of image processing and sperm head morphometry. Haematoxylin is the staining technique of choice for Cynomolgus spermatozoa, as optimum contrast of sperm heads with the surrounding background allows efficient segmentation, i.e. sperm head boundary detection, making the i…

endocrine systemurogenital systemSperm HeadUrologyEndocrinology Diabetes and MetabolismAnatomyHaematoxylinBiologySpermStainStainingComputer assisted image analysischemistry.chemical_compoundReproductive MedicinechemistrySperm morphologySampling (medicine)reproductive and urinary physiologyInternational Journal of Andrology
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