Search results for " Boundary conditions"
showing 10 items of 87 documents
Phase transitions in thin films with competing surface fields and gradients.
2011
As a generic model for phase equilibria under confinement in a thin-film geometry in the presence of a gradient in the field conjugate to the order parameter, an Ising-lattice gas system is studied by both Monte Carlo simulations and a phenomenological theory. Choosing an $L\ifmmode\times\else\texttimes\fi{}L\ifmmode\times\else\texttimes\fi{}D$ geometry with $L\ensuremath{\gg}D$ and periodic boundary conditions in the $x,y$ directions, we place competing surface fields on the two $L\ifmmode\times\else\texttimes\fi{}L$ surfaces. In addition, a field gradient $g$ is present in the $z$ direction across the film, in competition with the surface fields. At temperatures $T$ exceeding the critical…
Absence of hyperscaling violations for phase transitions with positive specific heat exponent
1994
Finite size scaling theory and hyperscaling are analyzed in the ensemble limit which differs from the finite size scaling limit. Different scaling limits are discussed. Hyperscaling relations are related to the identification of thermodynamics as the infinite volume limit of statistical mechanics. This identification combined with finite ensemble scaling leads to the conclusion that hyperscaling relations cannot be violated for phase transitions with strictly positive specific heat exponent. The ensemble limit allows to derive analytical expressions for the universal part of the finite size scaling functions at the critical point. The analytical expressions are given in terms of generalH-fu…
Multicanonical Monte Carlo study and analysis of tails for the order-parameter distribution of the two-dimensional Ising model.
2003
The tails of the critical order-parameter distribution of the two-dimensional Ising model are investigated through extensive multicanonical Monte Carlo simulations. Results for fixed boundary conditions are reported here, and compared with known results for periodic boundary conditions. Clear numerical evidence for ‘‘fat’’ stretched exponential tails exists below the critical temperature, indicating the possible presence of fat tails at the critical temperature. Our work suggests that the true order-parameter distribution at the critical temperature must be considered to be unknown at present.
Wetting in fluid systems. Wetting and capillary condensation of lattice gases in thin film geometry
1994
Monte Carlo studies of lattice gas models with attractive interactions between nearest neighbors on a simple cubic lattice are carried out for a L×L×D geometry with two hard walls of size L×L and periodic boundary conditions parallel to the wall. Two types of short-range forces at the walls are considered: (i) Both walls are of the same type and exert an attractive force of the same strength (in Ising model terminology, surface fields HD = H1 occur). (ii) The walls differ, one attracts and the other repels particles, again with the same strength (HD = −H1). In the first case, capillary condensation occurs at a chemical potential differing from its value for phase coexistence in the bulk, an…
Green’s function and existence of solutions for a third-order three-point boundary value problem
2019
The solutions of third-order three-point boundary value problem x‘‘‘ + f(t, x) = 0, t ∈ [a, b], x(a) = x‘(a) = 0, x(b) = kx(η), where η ∈ (a, b), k ∈ R, f ∈ C([a, b] × R, R) and f(t, 0) ≠ 0, are the subject of this investigation. In order to establish existence and uniqueness results for the solutions, attention is focused on applications of the corresponding Green’s function. As an application, also one example is given to illustrate the result. Keywords: Green’s function, nonlinear boundary value problems, three-point boundary conditions, existence and uniqueness of solutions.
Existence of a unique solution for a third-order boundary value problem with nonlocal conditions of integral type
2021
The existence of a unique solution for a third-order boundary value problem with integral condition is proved in several ways. The main tools in the proofs are the Banach fixed point theorem and the Rus’s fixed point theorem. To compare the applicability of the obtained results, some examples are considered.
CFD prediction of scalar transport in thin channels for reverse electrodialysis
2014
Reverse ElectroDialysis (RED) is a very promising technology allowing the electrochemical potential difference of a salinity gradient to be directly converted into electric energy. The fluid dynamics optimization of the thin channels used in RED is still an open problem. The present preliminary work focuses on the Computational Fluid Dynamics (CFD) simulation of the flow and concentration fields in these channels. In particular three different configurations were investigated: a channel unprovided with a spacer (empty channel) and two channels filled with spacers, one made of overlapped filaments the other of woven filaments. The transport of two passive scalars, representative of the ions …
A method to transform a nonlocal model into a gradient one within elasticity and plasticity
2014
Abstract A method based on the principle of the virtual power (PVP) is presented, by which a mechanical problem of nonlocal elasticity, or plasticity, is transformed into one of gradient nature. Different Taylor series expansion techniques are applied to the driving local strain fields of the nonlocal problem, either full spatial expansion within the bulk volume, or uni-directional expansion along the normal to the thin boundary layer. This, at the limit when the boundary layer thickness tends to zero, makes the PVP of the nonlocal model transform itself into one featuring a counterpart gradient model. Also, for a class of “associated” nonlocal and gradient elasticity models (i.e. the kerne…
Self-Assembly of Polymeric Particles in Poiseuille Flow: A Hybrid Lattice Boltzmann/External Potential Dynamics Simulation Study
2017
We present a hybrid simulation method which allows one to study the dynamical evolution of self-assembling (co)polymer solutions in the presence of hydrodynamic interactions. The method combines an established dynamic density functional theory for polymers that accounts for the nonlocal character of chain dynamics at the level of the Rouse model, the external potential dynamics (EPD) model, with an established Navier–Stokes solver, the Lattice Boltzmann (LB) method. We apply the method to study the self-assembly of nanoparticles and vesicles in two-dimensional copolymer solutions in a typical microchannel Poiseuille flow profile. The simulations start from fully mixed systems which are sudd…
Partition function of the trigonometric SOS model with reflecting end
2010
We compute the partition function of the trigonometric SOS model with one reflecting end and domain wall type boundary conditions. We show that in this case, instead of a sum of determinants obtained by Rosengren for the SOS model on a square lattice without reflection, the partition function can be represented as a single Izergin determinant. This result is crucial for the study of the Bethe vectors of the spin chains with non-diagonal boundary terms.