Search results for " COMBUSTION"
showing 10 items of 106 documents
Characterization of Biodiesel from Vegetable Oil Using Comprehensive Two-Dimensional Gas Chromatography
2012
Biodiesel from vegetable oils has been analyzed and its suitability for internal combustion engines has been assessed. The Standard biofuel’s characteristics have been investigated. Gas chromatography (GC) tests were carried out to characterize the fatty acid behavior. It was found that the mass percentage of saturated fatty acids did not change substantially with time, while unsaturated fatty acids increased with time for both B100 and B30. An increase in density for B100 and B30 with time was noted. Biodiesel density was within the standardization. The calorific values of biodiesel and its blend increased with time. Higher heating value for B100 increased from 41 to 43 MJ/kg while B30 inc…
Environmental analysis of chlorinated aromatic thioethers, sulphoxides and sulphones
1993
Abstract Chlorinated aromatic thioethers discussed here are polychlorinated dibenzothiophenes, thianthrenes and diphenylsulphides. Relatively little is known about their occurrence, behaviour and fate in the environment. Polychlorinated dibenzothiophenes and diphenylsulphides have recently been found to be formed in waste combustion and analysed in pulp mill effluents. Chlorinated sulphoxides and sulphones are usually metabolites or oxidation products of different chlorinated aromatic compounds. Different gas chromatographic-mass spectrometric techniques are used in the analysis of the chlorinated thioethers. The sulphoxides and sulphones, because of their higher polarity, can be isolated f…
Synthesis of high surface area perovskite catalysts by non-conventional routes
1997
Abstract The use of rare earth-containing perovskite oxides as total oxidation catalysts faces to the difficulty of obtaining high surface area materials and the need of calcination at high temperatures for its synthesis. In this work, perovskite NdCoO3 catalysts with relatively high surface areas were synthesized at soft calcination conditions by two non-conventional routes: heteronuclear organic complexes and amorphous precursors obtained by freeze-drying of nitrates solutions. Depending on the method used, different degrees of homogeneity in the bulk distribution of the component cations, oxygen non-stoichiometry as well as surface Co/Nd atomic ratios are obtained. In this way, the synth…
Catalytic combustion of ethane over high surface area Ln1−xKxMnO3 (Ln = La, Nd) perovskites: The effect of potassium substitution
1997
Publisher Summary As a general trend, the substitution of the rare earth cation by potassium decreased the intrinsic activity, reduced the reaction order in oxygen, and, for the more substituted samples (x>0.10), it increased the selectivity to ethene. Supported platinum or palladium catalysts have so far been used almost exclusively, because of their excellent activity. However, their high price, tendency to be poisoned, and volatility in some applications have estimulated the search for suitable substitutes. LaCoO3, as a potential auto exhaust catalyst, starting a wide interest in the catalytic properties of perovskites. Their specific application as catalysts in flameless combustion has …
Physical properties of aerosol particles measured from a bubbling fluidized bed boiler
2015
Abstract Increased use of biomass and waste fuels, and the consequent corrosion problem have led to an increased need to study and monitor the combustion processes. This study presents an extensive physical characterization of aerosol particles measured from a bubbling fluidized bed boiler with different fuel mixtures and optional ferric sulfate feeding. The fuel mixtures included bark, sludge, peat and solid recovered fuel. Previously, the characterization of the particles analyzed from a fluidized bed reactor has mainly focused on chemical off-line analysis of collected impactor samples, large coarse mode particles or laboratory-scale reactors. In this study, the focus is in the particle …
Preliminary Experimental Study on Double Fuel HCCI Combustion
2015
AbstractThis paper regards an experimental study on a particular internal combustion engine process which combines Double Fuel combustion with Homogeneous Charge Compression Ignition (HCCI) using mixtures of natural gas (NG) and gasoline. The tests performed on a CFR engine demonstrate that HCCI combustion can be achieved using NG-gasoline mixtures without knocking occurrence for low to medium engine load varying the proportion between the two fuels. The main advantage of this new combustion process relies on the noticeable higher engine efficiency obtained with respect to conventional spark ignition operation, and on the strong reduction of NOX emissions.
Promoting the activity and selectivity of high surface area Ni–Ce–O mixed oxides by gold deposition for VOC catalytic combustion
2011
Gold supported on nickel cerium oxide catalysts (Ni–Ce–O) have been studied for the total oxidation of propane, as a model for hydrocarbon volatile organic compound emission control. High surface area Ni–Ce–O catalysts were synthesized using a very simple evaporation method, where cerium and nickel salts were evaporated in the presence of a mixture of methanol and oxalic acid. Gold catalysts were prepared following a deposition–precipitation method. A very efficient catalyst for the oxidation of propane, in terms of both activity and selectivity, was obtained. This high activity has been related to the high surface area of the catalyst (and therefore to the presence of more active sites ava…
THE POSSIBILITY OF DISPOSING OF SPENT COFFEE GROUND WITH ENERGY RECYCLING
2015
The current policy of waste management requires, above all, a gradual reduction of waste amount and, to a larger extent, forces us to seek new methods of waste disposal. Recycling the energy contained in biomass waste is a more and more universally applied method of thermal converting. Biomass combustion allows saving fossil fuels which fits into sustainable development. This paper checks the possibility of using spent coffee ground (SCG) in energy recycling using a combustion process. This particular biomass type up to now has not been widely examined, which inclines to consider its usage as a potential additive to alternative fuels. In the study, we examined the quality of fuel, which was…
Influence of Biomass Combustion Products on Element Content and Thermal Stability of Latvian Sheep Breed Wool Filter Fibres
2020
Sheep wool is natural, easy obtainable, renewable and biodegradable material with a perspective application as a sorbent in filters for purification of industrial emissions from various environmental pollutants. The element content and thermal stability of Latvian dark-headed sheep wool filter fibres was analysed and described before and after exposure to biomass combustion products. Based on the obtained results, it is concluded that the sheep wool filter fibres can sorb various gaseous combustion products, such as carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx), however, the sorption processes of these gases are irreversible. The obtained results of total reflection X…