Search results for " COMPUTATION"
showing 10 items of 1478 documents
Rapid self-healing and anion selectivity in metallosupramolecular gels assisted by fluorine-fluorine interactions.
2017
Simple ML2 [M = Fe(II), Co(II), Ni(II)] complexes obtained from a perfluoroalkylamide derivative of 4-aminophenyl-2,2′,6,2′-terpyridine spontaneously, yet anion selectively, self-assemble into gels, which manifest an unprecedented rapid gel strength recovery, viz. self-healing, and thermal rearrangement in aqueous dimethyl sulfoxide. The key factor for gelation and rheological properties emerges from the fluorine–fluorine interactions between the perfluorinated chains, as the corresponding hydrocarbon derivative did not form metallogels. The perfluoro-terpyridine ligand alone formed single crystals, while its Fe(II), Co(II) or Ni(II) complexes underwent rapid gelation leading to highly enta…
Updating strategies for distance based classification model with recursive least squares
2022
Abstract. The idea is to create a self-learning Minimal Learning Machine (MLM) model that is computationally efficient, easy to implement and performs with high accuracy. The study has two hypotheses. Experiment A examines the possibilities of introducing new classes with Recursive Least Squares (RLS) updates for the pre-trained self learning-MLM model. The idea of experiment B is to simulate the push broom spectral imagers working principles, update and test the model based on a stream of pixel spectrum lines on a continuous scanning process. Experiment B aims to train the model with a significantly small amount of labelled reference points and update it continuously with (RLS) to reach ma…
Lyapunov quantities and limit cycles in two-dimensional dynamical systems : analytical methods, symbolic computation and visualization
2011
Robustness of asymmetry and coherence of quantum states
2016
Quantum states may exhibit asymmetry with respect to the action of a given group. Such an asymmetry of states can be considered as a resource in applications such as quantum metrology, and it is a concept that encompasses quantum coherence as a special case. We introduce explicitly and study the robustness of asymmetry, a quantifier of asymmetry of states that we prove to have many attractive properties, including efficient numerical computability via semidefinite programming, and an operational interpretation in a channel discrimination context. We also introduce the notion of asymmetry witnesses, whose measurement in a laboratory detects the presence of asymmetry. We prove that properly c…
Quantum memories with zero-energy Majorana modes and experimental constraints
2016
In this work we address the problem of realizing a reliable quantum memory based on zero-energy Majorana modes in the presence of experimental constraints on the operations aimed at recovering the information. In particular, we characterize the best recovery operation acting only on the zero-energy Majorana modes and the memory fidelity that can be therewith achieved. In order to understand the effect of such restriction, we discuss two examples of noise models acting on the topological system and compare the amount of information that can be recovered by accessing either the whole system, or the zero-modes only, with particular attention to the scaling with the size of the system and the e…
Data from: Extinction and recolonization of maritime Antarctica in the limpet Nacella concinna (Strebel, 1908) during the last glacial cycle: toward …
2013
Quaternary glaciations in Antarctica drastically modified geographical ranges and population sizes of marine benthic invertebrates and thus affected the amount and distribution of intraspecific genetic variation. Here, we present new genetic information in the Antarctic limpet Nacella concinna, a dominant Antarctic benthic species along shallow ice-free rocky ecosystems. We examined the patterns of genetic diversity and structure in this broadcast spawner along maritime Antarctica and from the peri-Antarctic island of South Georgia. Genetic analyses showed that N. concinna represents a single panmictic unit in maritime Antarctic. Low levels of genetic diversity characterized this population…
Synthesis, computational evaluation and pharmacological assessment of acetylsalicylic esters as anti-inflammatory agents
2019
A convenient approach to the synthesis of alkyl esters of aspirin (ASA-OR) has been developed. The synthesis of ASA-OR has been realized in two steps: (1) direct esterification of salicylic acid with alcohols in the presence of dicyclohexylcarbodiimide to give alkyl salicylates (SAL-OR); (2) acetylation of SAL-OR with acetyl chloride to yield ASA-OR. Molecular mechanics simulations, performed to calculate the kinetic radii of several ASA-OR, indicated that the pentyl and hexyl acetylsalicylates possess the best properties to cross cell membranes. The in vitro biological tests demonstrate their anti-inflammatory activity, superimposable to that of aspirin. The results of our study suggest th…
An Integrated Framework for Web Services Orchestration
2009
International audience; Currently, Web services give place to active research and this is due both to industrial and theoretical factors. On one hand, Web services are essential as the design model of applications dedicated to the electronic business. On the other hand, this model aims to become one of the major formalisms for the design of distributed and cooperative applications in an open environment (the Internet). In this article, the authors will focus on two features of Web services. The first one concerns the interaction problem: given the interaction protocol of a Web service described in BPEL, how to generate the appropriate client? Their approach is based on a formal semantics fo…
Postoperative Lens Position Preoperatively Determined by Scheimpflug Photography
1999
The position of the artificial lens has an important influence on refractive power calculation. We compared the position of the crystalline lens with that of the artificial lens after cataract surgery by means of Scheimpflug photography. A difference in position of approximately 0.8 mm in the anterior direction could be determined.