Search results for " Car"

Simulating speleothem growth in the laboratory: Determination of the stable isotope fractionation (δ13C and δ18O) between H2O, DIC and CaCO3

2019

Abstract Here we present novel cave-analogue experiments directly investigating stable carbon and oxygen isotope fractionation between the major involved species of the carbonate system (HCO3−, CO2, CaCO3 and H2O). In these experiments, which were performed under controlled conditions inside a climate box, a thin film of solution flew down an inclined marble or glass plate. After different distances of flow and, thus, residence times on the plate, pH, electrical conductivity, supersaturation with respect to calcite, precipitation rate as well as the δ18O and δ13C values of the dissolved inorganic carbon (DIC) and the precipitated CaCO3 were obtained. Progressive precipitation of CaCO3 along…

Sequence stratigraphy and carbon isotope stratigraphy of an Aptian mixed carbonate-siliciclastic platform to basin transition (Galve sub-basin, NE Sp…

2010

Reconstructing caribou seasonal biogeography in Little Ice Age (late Holocene) Western Alaska using intra-tooth strontium and oxygen isotope analysis

2019

Abstract The palaeobiogeography of key prey-species can provide valuable insights into animal-human interactions, human subsistence activities and landscape use in the past. In many contemporary indigenous Arctic societies, caribou (Rangifer tarandus spp.) are an important seasonal subsistence species, and recent climatic shifts have influenced the seasonal and spatial distribution and migrations of herds. The impact of larger scale climatic change on this species, such as that experienced during the Little Ice Age (LIA), is not known, but may provide vital clues about future variability. Here we present sequential strontium (87Sr/86Sr) and oxygen (δ18OCO3) isotope data from archaeological …

Chemical and mineralogical analyses on stones from Sagunto Castle (Spain)

2019

Abstract For the first time, an archaeometric study was carried out on the carbonate rock ashlars of the Sagunto Castle. The studied site is one of the most important and best preserved Spanish archaeological and architectural monuments, characterized by different construction phases from the Roman period to Modern Ages. Forty samples collected from thirteen different structures of Sagunto Castle and two quarries, located in the Sagunto's hill were used for comparative purposes. The samples were analyzed by X-ray diffraction, X-ray fluorescence and inductively coupled plasma mass spectrometry to determine their mineralogical and elemental composition. The obtained data show similar chemical…

Detailed record of the mid-Oxfordian (Late Jurassic) positive carbon-isotope excursion in two hemipelagic sections (France and Switzerland): A plate …

2007

14 pages; International audience; The Oxfordian (Late Jurassic) was a time of widespread change in Jurassic marine (carbonate) sedimentation patterns. A marked positive excursion in δ13C is dated as Middle Oxfordian in age. In this study we investigate if changes in carbonate sedimentation coincided with altered carbon cycling and climate. We use C-isotope records as a proxy for the evolution of the carbon cycle and compare δ13C-trends with the evolution of sedimentation in a segment of the opening Tethys seaway. One of the studied sections is located in the Subalpine basin of France (Trescléoux and Oze), the other in the Swiss Jura mountains (Liesberg). Carbon-isotope stratigraphy of carbo…

The relationships between soft-sediment deformation structures and synsedimentary extensional tectonics in Upper Triassic deep-water carbonate succes…

2016

Abstract We describe soft-sediment deformation structures into the Upper Triassic cherty limestone outcropping in the Pizzo Lupo section (Central Sicily, Italy), pertaining to the deep-water palaeodomain of the Southern Tethyan margin. In the study section, mainly consisting of thin-bedded mudstone/marl alternations with bedded chert intercalations, some lithofacies have been separated on the basis of the abundance of the calcium carbonate/clay content and the overall textural features. The deformational structures, displaying different deformational styles as folded and faulted beds, disturbed layers, clastic dikes, and slumps occur mainly in the deformed horizons that involve marl-dominat…

Structure and evolution of a Messinian mixed carbonate-siliciclastic platform: the role of evaporites (Sorbas Basin, South-east Spain).

2010

36 pages; International audience; The Sorbas Member is a late Messinian complex sedimentary systemthat formed immediately following deposition of the Messinian evaporites in the Sorbas Basin (South-east Spain). This work describes the sequence architecture and facies organization of a continuous kilometre long, alluvial fan to open platform transect near the village of Cariatiz in the north-east of the basin. The postevaporitic Cariatiz platform was a mixed carbonate-siliciclastic system composed of four intermediate-frequency, fifth-order depositional sequences (Depositional Sequences 1 to 4) arranged in an overall prograding trend. The intense fracturing and brecciation of these deposits …

Conjunctive use of spectral gamma-ray logs and clay mineralogy in defining late Jurassic-early Cretaceous palaeoclimate change (Dorset, U.K.).

2006

Abstract Detrital clay mineralogy is controlled by weathered source rock, climate, transport and deposition that in turn influence the spectral gamma-ray (SGR) response of resultant sediments. Whilst a palaeoclimate signal in clay mineralogy has been established in some ancient successions, the SGR response remains contentious, largely because the data sets have yet to be collected at the same or appropriate vertical scales to allow comparison. In addition, the influence of organic matter on SGR is not always considered. Here, we present clay mineralogical, total organic carbon (TOC) and SGR analyses from the late Jurassic and early Cretaceous of the Wessex Basin, a period of previously doc…

Influence of dissolved organic matter on rare earth elements and yttrium distributions in coastal waters

2010

International audience; Data collected during this study indicate that dissolved Y and REE (rare earth element) behaviour can be monitored through shale-normalised ratios. Relationships occurring between these ratios suggest that leaching from lithogenic materials is the main source of REE in the studied area. This process involves riverine detrital matter in the inner area of the Gulf of Palermo. Features of shale-normalised patterns and the relationship recognised between dissolved Fe and Y/Ho suggest that REE are released from Fe-rich coatings of atmospheric dust. Observed similarities between dissolved Fe and chlorophyll- content suggest that leaching of Fe-rich atmospheric particulates…

The end-Triassic mass extinction: A new correlation between extinction events and δ13C fluctuations from a Triassic-Jurassic peritidal succession in …

2018

Abstract A new δ13Ccarb curve was obtained from an expanded peritidal succession in western Sicily and was used to investigate the relationships between isotopic signatures and biological events on carbonate platforms across the Triassic-Jurassic boundary (TJB). The resulting curve shows two main negative carbon isotopic excursions (CIEs) that fit well with the “Initial” and “Main” CIEs that are recognized worldwide and linked to the End-Triassic Extinction (ETE). In the studied section, the first negative CIE marks the disappearance of the large megalodontids, which were replaced by small and thin-shelled specimens, while the “Main” CIE corresponds to the last occurrence (LO) of the megalo…