Search results for " Carbonates"
showing 5 items of 45 documents
Cementing agents involved in the macro- and microaggregation of a Mediterranean shrubland soil under laboratory heating
2014
The heating effect on aggregation and cementing agents of a Mediterranean soil was studied in two fractions (macro- and microaggregates) in different environments: under Quercus coccifera soil (UQ), under Rosmarinus officinalis soil (UR) and between plants or bare soil (BS). Samples were heated under laboratory conditions at different temperatures (220, 380, 500, 750 and 1000. °C) to establish their effects on the studied soil properties by comparison with unheated control samples (25. °C). Increasing temperature treatments caused significant changes in most soil variables. In both soil fractions, the presence of vegetation contributed to increase of the soil organic matter (SOM) content, w…
Double-CO32− Centered [CoII5] Wheel and Modeling of Its Magnetic Properties
2010
A high-spin Co(II) cluster with a rare pentagonal molecular structure and formula [Co(5)(CO(3))(2)(bpp)(5)]ClO(4) (1; Hbpp is 2,6-bis(phenyliminomethyl)-4-methylphenolate) has been synthesized and characterized by single-crystal X-ray diffraction. This topology arises from fusing five [Co(2)(bpp)] moieties in a cyclic manner around two CO(3)(2-) central ligands, resulting in propeller-like configuration. The irregular coordination of the carbonate ions to the metal centers results in a combination of coordination numbers (CNs) of the Co(II) ions of five and six. The bulk magnetization of this complicated magnetically exchanged system has been modeled successfully by employing a matrix diago…
Lowstand carbonates, highstand sandstones?
2003
The sedimentary facies, sediment dynamics and sequence architecture of modern high-energy shelves in the mid and high latitudes are largely governed by wave abrasion processes. Cool-water carbonates may form there, if the influx and/or net accretion of siliciclastics is kept at a minimum. Little dilution of the carbonate produced in situ is generally promoted by a wide "epicontinental" shelf, subdued topography of the adjacent mainland, the predominance of limestone outcrops, and an arid climate. The aforementioned requirements are rarely met, and thus will automatically lead to the formation of mixed siliciclastic-cool-water carbonates. Such an example is found in the Early to Mid-Miocene …
Formation of microbial organic carbonates during the Late Jurassic from the Northern Tethys (Amu Darya Basin, Uzbekistan): implications for Jurassic …
2020
23 pages; International audience; The Late Jurassic was a period of major global carbon cycle perturbations with episodes of anoxia leading to regional accumulation of organic matter in sediments worldwide. The Tubiegatan section (SW Gissar Mountains, Uzbekistan) located in the Northern Tethys, shows atypical organic-rich limestone and marl deposits (up to 6% of total organic carbon) marked by pronounced negative excursions of δ13Ccarb (amplitude of ca. 12‰) and δ13Corg (amplitude of ca. 4‰) recorded during the Middle Oxfordian (Transversarium Zone). A transdisciplinary approach including sedimentology, palynofacies characterization, mineralogy, organic and inorganic geochemistry was carrie…
Raman Investigations to Identify Corallium rubrum in Iron Age Jewelry and Ornaments
2016
International audience; During the Central European Iron Age, more specifically between 600 and 100 BC, red precious corals (Corallium rubrum) became very popular in many regions, often associated with the so-called (early) Celts. Red corals are ideally suited to investigate several key questions of Iron Age research, like trade patterns or social and economic structures. While it is fairly easy to distinguish modern C. rubrum from bone, ivory or shells, archaeologists are confronted with ancient, hence altered, artifacts. Due to ageing processes, archaeological corals lose their intensive red color and shiny surface and can easily be confused with these other light colored materials. We pr…