Search results for " Characterization"
showing 10 items of 310 documents
Electro-optical characterization of ruthenium-based dye sensitized solar cells: A study of light soaking, ageing and temperature effects
2017
Abstract In this work, we report on the electro-optical characterization of Dye Sensitized Solar Cells (DSSCs) which use ruthenium complexes as sensitizers. In particular, several kinds of measurements have been performed to study the electrical performances and the efficiency levels of the cells at different operating conditions. In detail, the measurements have been conducted at varying temperatures and hours of light soaking. Our results show that the short circuit current density J SC , the open circuit voltage V OC and the conversion efficiency η increase with the hours of light soaking, while they decrease with temperature. A thorough investigation on the light soaking process at the …
One diode circuital model of light soaking phenomena in Dye-Sensitized Solar Cells
2018
Abstract In this work, we report on the modelling of light soaking effect on Ruthenium-based Dye Sensitized Solar cells (DSSCs). Such a phenomenon can be detected when exposing the cells at increasing hours of illumination and produces a reversible performance increase. Starting from the results obtained through the electro-optical characterization of the cells, we applied a one-diode circuital-model. Our results show a good agreement between the experimental and the simulated data, with a mean square error in the order of 10−12 and a maximum error in current lower than 0.6%. Finally such results allowed us to infer some precise trends followed by the cells main electrical parameters and of…
The effect of hydration layers on the anodic growth and on the dielectric properties of Al2O3 for electrolytic capacitors
2014
Hydrous films were grown on high purity and cubicity Al foils for electrolytic capacitors in deionized water, ethylene glycol - deionized water and in glycerol - deionized water for different immersion times. According to the X-ray diffraction patterns the hydration treatment allowed to grow a pseudo boehmite layer on Al surface whose morphology is appreciably affected by the bath composition. Capacitance measurements and photoelectrochemical findings suggest that a more compact barrier layer forms during the immersion in alcohol containing solutions. The hydration in water allowed to save energy and to prepare more blocking oxide films. The beneficial effect of hydration in hot water on th…
Understanding the regioselectivity in hetero Diels–Alder reactions. An ELF analysis of the reaction between nitrosoethylene and 1-vinylpyrrolidine
2013
[EN] The regioselectivity in the hetero Diels-Alder reaction between nitrosoethylene 1 and 1-vinylpyrrolidine 2 has been studied by a comparative ELF bonding analysis along the IRC of the endo/ortho and endo/meta regioisomeric channels at the B3LYP/6-31G*. level. Along the most favorable endo/ortho regioisomeric channel, the C-C sigma bond is first formed by coupling of two pseudoradical centers located at the most electrophilic carbon of 1 and the most nucleophilic center of 2. Formation of these relevant pseudoradical centers, which depend on the total charge transfer process along the polar reaction, and not on the approach mode of each reagent, is well characterized by analysis of the a…
Upgrading Treatment and Molecular Diagnosis in Endometrial Cancer-Driving New Tools for Endometrial Preservation?
2023
One emerging problem for onco-gynecologists is the incidence of premenopausal patients under 40 years of age diagnosed with stage I Endometrial Cancer (EC) who want to preserve their fertility. Our review aims to define a primary risk assessment that can help fertility experts and onco-gynecologists tailor personalized treatment and fertility-preserving strategies for fertile patients wishing to have children. We confirm that risk factors such as myometrial invasion and The International Federation of Gynecology and Obstetrics (FIGO) staging should be integrated into the novel molecular classification provided by The Cancer Genome Atlas (TCGA). We also corroborate the influence of classical…
Geomaterials in green building practices: comparative characterization of commercially available clay-based plasters
2013
Three pre-mixed powdered clay-based (earthen) plasters produced in Europe and specifically designed for wall undercoating were analyzed in this paper. These materials are commercially available and successfully employed in green building practices all over the world. Their compositional and textural characteristics, as well as plastic behaviour were investigated through a multi-analytical approach: X-ray powder diffraction (XRPD), polarized light microscopy (PLM), X-ray fluorescence spectrometry (XRFS), scanning electron microscopy equipped with an energy dispersive spectrometer (SEM-EDS), mercury intrusion porosimetry (MIP), grain-size distribution (GSD) and semi-empirical tests (Atterberg…
Unit Vector Fields that are Critical Points of the Volume and of the Energy: Characterization and Examples
2007
In the last few years, many works have appeared containing examples and general results on harmonicity and minimality of vector fields in different geometrical situations. This survey will be devoted to describe many of the known examples, as well as the general results from where they are obtained.
Quality Assurance and Support Measures for Solar Cooling on System Level
2016
Abstract Within the IEA SHC Task 48 “Quality assurance and support measures for Solar Cooling” the analysis and evaluation of the systems has been one of the four main focuses. Here the activities are including the lab- and field-based characterization of the systems, the definition and application of performance figures, a guideline for a reliable monitoring procedure including methods for automated error detection and an updated overview on worldwide installed DEC systems including hints and good practice examples. They are furthermore leading to three different easy-to-use tools for solar cooling systems: The LCA tool considers environmental and energetic values for the evaluation, the P…
CIGS PV Module Characteristic Curves Under Chemical Composition and Thickness Variations
2014
This paper analyzes how the electrical characteristics of a CIGS photovoltaic module are affected by the chemical composition and by the thickness variations of the CIGS absorber. The electrical characteristics here considered are the short circuit current, the open circuit voltage, the efficiency and the power peak. The chemical composition is varied by tuning the ratio between gallium and indium. This analysis has been performed by means of the wxAMPS software, developed by the University of Illinois. The above variations have been taken into account on a PV module made of 72 cells. This analysis has been carried out employing a PV module mathematical model developed and implemented by th…
NB PLC and Software Defined Networking for Smart Grid Applications
2017
During the last years, the installation of Distributed Energy Resources (DERs) and the expected diffusion of Electrical Vehicles (EVs), is increasing the complexity of the distribution grid, making the management of the grid operated by Distribution System Operators (DSOs) more difficult. The Smart Grid approach tries to provide a response to these troubles, by means of a strong interaction between the power grid and Information and Communication Technology (ICT) infrastructures. The drawback of this approach is an increase in the management effort of the ICT infrastructures, for which the DSO are not prepared. Software Defined Networking (SDN) is an approach developed to manage complex ICT…