Search results for " Chemical Engineering"
showing 10 items of 2965 documents
Heat treatment of vegetable oils. II. GC-MS and GC-FTIR spectra of some isolated cyclic fatty acid monomers
1987
Gas liquid chromatography coupled with mass spectrometry (GC-MS) showed that the cyclic fatty acid monomers (CFAM) isolated from a heated linseed oil have two ethylenic bonds, while the CFAM isolated from heated sunflower oils were saturated and monoethylenic isomers. GC-MS studies also showed the presence of cyclohexenic derivatives in the case of linseed oil.
Enhancement of structural, functional and antioxidant properties of fish gelatin films using Maillard reactions
2018
International audience; This study investigates the effect of Maillard reactions (MR) on the physico-chemical and biological properties of fish gelatin based edible films. Glucose was incorporated in gelatin film forming solutions at different glucose/lysine molar ratios: 0.5/1.0, 1.0/1.0 and 5.0/1.0. The MR was then induced by heating films at 90 °C for 24 h in dry conditions. Color changes and browning index measurements were used to pursue the MR kinetic. Results showed that the development of MR products was dependent on the glucose content and on the reaction time. Mechanical and thermal properties of treated films displayed an increase in tensile strength, elongation at break and glas…
Novel functional chitosan and pectin bio-based packaging films with encapsulated Opuntia-ficus indica waste
2021
Abstract The aim of this work was to study the effect of adding red prickly pear, as wasted source of antioxidants on various characteristics of novel functional (antioxidant) chitosan and pectin film formulations. Four types of prickly pear material were used: fruit pulp or peel, as powdered extracts and as aqueous extracts. Prickly pear peel extract was shown to possess higher antioxidant properties than fruit pulp. The antioxidant power of extracts was pretty high, around 1000 mgAAE∙100 g−1 for extract and that of all films around 100 mgAAE∙100 g−1 for films. Even though some changes in thickness, moisture content, water solubility, oxygen permeability and water vapor permeability of fil…
Inductively coupled plasma optical emission spectroscopy determination of trace element composition of argan oil.
2011
A methodology based on inductively coupled plasma optical emission spectroscopy (ICP-OES) after microwave assisted acid digestion has been developed to determine the trace element content of Moroccan argan oil. Limit of detection values equal or lower than few mg/kg were obtained for all elements under study. To assure the accuracy of the whole procedure, recovery studies were carried out on argan oil samples spiked at different concentration levels from 10 to 200 µg/L. Quantitative average recovery values were obtained for all elements evaluated, demonstrating the suitability of this methodology for the determination of trace elements in argan oil samples. Aluminum, calcium, chromium, iro…
Reduction of saturated fat in chocolate by using sunflower oil-hydroxypropyl methylcellulose based oleogels
2021
The suitability of sunflower oil-hydroxypropyl methylcellulose (HPMC) based oleogel obtained by emulsion template approach as partial cocoa butter (CB) replacer in chocolates was investigated. A level of 50% CB replacement was optimum, as higher level of replacement affected the sensory appearance in comparison to the control chocolate (without added oleogel). Four levels of HPMC (0.5, 1, 1.5 and 2%) were considered. Textural and calorimetric properties, as well as sensory properties obtained by Free Choice Profile of the formulated chocolates were investigated. Partial replacement of CB by the sunflower-HPMC based oleogel reduced significantly the chocolate hardness. Higher HPMC concentrat…
Spectroscopic analyses of the influence of electron beam irradiation doses on mechanical, transport properties and microstructure of chitosan-fish ge…
2015
International audience; The objective of this work was to better display the effect of electron beam accelerator doses (0, 20, 40 and 60 kGy) on structural, mechanical and barrier properties of edible lightly plasticized chitosan-fish gelatin blend film. From Electron Spin Resonance (ESR), signal at 3500 G for blend film was identified as free radical formation during irradiation, which might introduce intermolecular cross-linking into the polymer matrix, thus affecting structural properties. Tensile Strength (TS) for gelatin film significantly increased with growing irradiation doses (improved by 30% for 60 kGy), but the TS of chitosan and blend films were not significantly affected. On th…
Integral Extraction of Opuntia ficus-indica Peel Bioproducts via Microwave-Assisted Hydrodiffusion and Hydrodistillation
2019
The microwave-assisted hydrodiffusion extraction process affords high quality pectin and betanin from the peel of red and green Opuntia ficus-indica fruits under mild conditions. An aqueous mixture of valued bioproducts is readily obtained from the fruit peel cell water itself, without any water addition. The integral extract can be used as such to formulate nutraceutical beverages and products or, upon straightforward separation, to isolate pectin and betanin devoid of chemical contaminants suitable as ingredients for products ranging from food and beverage to cosmetic and pharmaceutical sectors. Betanin shows exceptional stability thanks to the high amounts of antioxidant polyphenols in t…
Transfers of small analytes in a multiphasic stirred fruit yoghurt model
2007
International audience; The transfer of small analytes in a multiphasic stirred fruit yoghurt model, made of a pectin gel aimed to mimic fruit pieces and of a dairy gel done with milk acidified by glucono-δ-lactone hydrolysis, have been studied. The concentration gradients between the pectin gel and the dairy gel were the driving force for the migration of small analytes (i.e. water, protons and colorants). Water migrated from the dairy to the pectin gel, causing modifications in the water content of both gels and an equilibration of their water activity at 0.938±0.003. Inversely, protons migrated from the pectin to the dairy gel. These changes in composition of both gels being likely to ha…
Application of Potassium Ion Impregnated Titanium Dioxide as Nanocatalyst for Transesterification of Linseed Oil
2018
The current work comprises the investigation of biodiesel production from linseed oil using TiO2 and a potassium L-tartrate monobasic (C4H5KO6)-modified TiO2 nanocatalyst. Different amounts of C4H5KO6 were considered for TiO2 modification. The nanocatalyst TiO2–0.5C4H5KO6 (1:0.5 molar ratio) showed the best conversion rate for biodiesel production. The nanocatalyst was characterized by FTIR, XRD, TEM, BET, and XPS, and the Hammett indicator–benzenecarboxylic acid titration method was used for basicity measurement. The biodiesel was characterized by GC-MS and 1H and 13C NMR. Furthermore, the optimum reaction parameters for transesterification reaction were analyzed, and the yield was determi…
Management of irrigation water and nutrient demands of tomato (Lycopersicon esculentum Mill.) using urban treated wastewater from a pilot-scale horiz…
2017
The reuse of treated wastewater (TWW) in crop irrigation is an advanced and rational approach to water resource management in agriculture. Results would seem to demonstrate that it could be an extremely important tool in the reduction of freshwater (FW) consumption in agriculture, at the same time helping to increase crop yields through the transfer of nutrients required for crop growth. In arid and semi-arid areas of the Mediterranean, constructed wetlands can play a key role in the treatment and reuse of wastewater due to their multifunctional nature. The aim of this study was to manage water and nutrient requirements of tomato (Lycopersicon esculentum Mill.) using TWW from a pilot-scale …