Search results for " Cluster"

showing 2 items of 2162 documents

On the convergence of zero-point vibrational corrections to nuclear shieldings and shielding anisotropies towards the complete basis set limit in wat…

2016

The method and basis set dependence of zero-point vibrational corrections (ZPVCs) to nuclear magnetic resonance shielding constants and anisotropies has been investigated using water as a test system. A systematic comparison has been made using the Hartree–Fock, second-order Møller–Plesset perturbation theory (MP2), coupled cluster singles and doubles (CCSD), coupled cluster singles and doubles with perturbative triples corrections (CCSD(T)) and Kohn–Sham density functional theory with the B3LYP exchange-correlation functional methods in combination with the second-order vibrational perturbation theory (VPT2) approach for the vibrational corrections. As basis sets, the correlation consisten…

waterBiophysicsZero-point energyzero-point vibrational correctionMonotonic function010402 general chemistry01 natural sciencesQuantum mechanics0103 physical sciencesPhysics::Atomic and Molecular ClustersCCSD(T)Limit (mathematics)complete basis set limitPhysics::Chemical PhysicsPhysical and Theoretical ChemistryMolecular BiologyBasis setPhysics010304 chemical physicsBasis (linear algebra)Condensed Matter PhysicsNMR shielding constant0104 chemical sciencesCoupled clusterDensity functional theoryPerturbation theory (quantum mechanics)Molecular Physics
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Work–Family Boundary Management Profiles in Two Finnish Samples : A Person-oriented Approach

2015

Background: The present study aims to identify different work-family boundary management profiles among Finnish employees, and examine how these relate to conflict between work and family or their mutual enrichment. Method: Participants from two samples, one consisting of university staff (n1 = 1,139) and another of nurses (n2 = 271), were asked to respond to an online survey concerning work-family boundary management, work-to-family enrichment, and work-to-family conflict scales. Results: A cluster analysis identified three profiles in both samples: segmentors, integrators and favoring family over work in the university sample, and segmentors, integrators and favoring work over family in t…

work-family conflictwork-family boundary managementApplied psychologydomain flexibilityFamily conflictSample (statistics)Disease clusterBoundary managementwork-family enrichmentPerson orientedWork (electrical)Operations managementPsychologyta515
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