Search results for " Coating."
showing 10 items of 2558 documents
Photophysical Investigation of Iron(II) Complexes Bearing Bidentate Annulated Isomeric Pyridine-NHC Ligands
2020
The possibility of achieving luminescent and photophysically active metal-organic compounds relies on the stabilization of charge transfer states and kinetically and thermodynamically blocking non-...
An empirical method to determine the free surface energy of solids at different deformations and temperatures regimes : An application to Al.
2005
Abstract We have performed molecular dynamics (MD) simulations using the three low index surfaces of Al to determine the variation of the surface energy as a function of deformation and temperature. We have also developed an empirical formulation for the surface free energy as a function of deformation. The observed difference between the numerical and analytical results has led us to divide the deformation into a mechanical and a thermal contribution. From this observation, we have obtained an expression for the surface free energy placing the temperature dependence on the bulk and surface elastic constants. Our simulations permitted us to analyze the multilayer relaxation for the particul…
Deviation from threshold model in ultrafast laser ablation of graphene at sub-micron scale
2015
International audience; We investigate a method to measure ultrafast laser ablation threshold with respect to spot size. We use structured complex beams to generate a pattern of craters in CVD graphene with a single laser pulse. A direct comparison between beam profile and SEM characterization allows us to determine the dependence of ablation probability on spot-size, for crater diameters ranging between 700 nm and 2.5 μm. We report a drastic decrease of ablation probability when the crater diameter is below 1 μm which we interpret in terms of free-carrier diffusion.
The 2014 Magnetism Roadmap
2014
Magnetism is a very fascinating and dynamic field. Especially in the last 30 years it has experienced many major advances in the full range from novel fundamental phenomena to new products. Applications such as hard disk drives and magnetic sensors are part of our daily life, and new applications, such as in non-volatile computer random access memory, are expected to surface shortly. Thus it is timely for describing the current status, and current and future challenges in the form of a Roadmap article. This 2014 Magnetism Roadmap provides a view on several selected, currently very active innovative developments. It consists of 12 sections, each written by an expert in the field and addressi…
Combined Temperature Radiation Effects and Influence of Drawing Conditions on Phosphorous‐Doped Optical Fibers
2018
International audience; This work focuses on the effects of high dose ionizing radiation, up to 10 MGy(SiO2), on P‐doped multimode optical fibers (OF) at different irradiation temperatures. The investigation is based on two complementary experimental techniques: radiation‐induced attenuation (RIA) measurements and electron paramagnetic resonance (EPR). The latter technique allows measuring the P1, P2, metastable‐POHC and stable‐POHC defects. Three OF samples are drawn from the same preform to evaluate the influence of changing their drawing conditions of the OFs on the radiation responses. This first study is performed under X‐rays at room temperature. The results are compared with the ones…
Porous architecture and thermal properties of thermal barrier coatings deposited by suspension plasma spray
2020
Abstract Besides the intrinsic low heat transfer capability of material, the thermal insulation property of thermal barrier coatings (TBCs) also relies on their microstructures. For better understanding the relationship between process parameters, porous architecture, and thermal properties of coatings, YSZ coatings were firstly manufactured by suspension plasma spray (SPS). Afterwards their total porosities were characterized by using the technique of X-ray transmission, the nano/submicro pores in those coatings were detected with Ultra-Small Angle X-ray Scattering (USAXS), and the thermal properties of coatings were measured using the laser flash method. The results indicated that: i) the…
Gas sensors arrays (electronic noses) : a study about the speed/accuracy ratio
2000
Abstract New Fingerprint Mass Spectra (FMS) systems claim for a higher precision, a reduced analysis time, and a lower drift, compared with Gas Sensors Arrays ‘Electronic Noses’. We demonstrated in this study that metal oxide gas sensors may have highly improved performances for both accuracy and run time, when used in optimum conditions. The different noise components were quantified referring to popular words (equivalent of ethanol concentration) using the transfer function of the sensor. It was pointed out that sample surrounding greatly affects the noise level, and that the signal-to-noise ratio may be dramatically increased, reducing the distortion generally assessed between sensor and…
Electronic noses : specify or disappear
2000
Abstract When the quality control is achieved by using GC or GC/MS, the apparatus must comply with the applicable norms, but what about “electronic noses”? End users demand for formal specifications for selectivity, sensitivity, repeatability and sample throughput. The behavioural modelling of electronic olfactometers may provide specifications for these required parameters. This will allow both the measure itself, and evaluate the influence of the experimental errors on the sample classification. Users may expect to find a methodology allowing the performances of systems to be checked before any final decision and during routine use. We have demonstrated that the system sensitivity and log…
Influence of interfering gases on a carbon monoxide differential sensor based on SAW devices functionalized with cobalt and copper corroles
2021
International audience; <!--[if gte mso 9]><xml> <w:WordDocument> <w:View>Normal</w:View> <w:Zoom>0</w:Zoom> <w:TrackMoves/> <w:TrackFormatting/> <w:HyphenationZone>21</w:HyphenationZone> <w:PunctuationKerning/> <w:ValidateAgainstSchemas/> <w:SaveIfXMLInvalid>false</w:SaveIfXMLInvalid> <w:IgnoreMixedContent>false</w:IgnoreMixedContent> <w:AlwaysShowPlaceholderText>false</w:AlwaysShowPlaceholderText> <w:DoNotPromoteQF/> <w:LidThemeOther>FR</w:LidThemeOther> <w:Compatibility> <w:BreakWrappedTables/> <w:SnapToGridInCell/> <w:WrapTextWithPunct/> <w:UseAsianBreakRules/> <w:DontGrowAutofit/> <w:SplitPgBreakAndParaMark/> <w:EnableOpenTypeKe…
Comportement en fatigue thermomécanique à haute température d’un système barrière thermique texturé par laser
2020
In service life of Thermal Barrier Coating (TBC) systems for blade applications can be limited by the top-coat (TC) spallation under thermo-mechanical fatigue (TMF) loadings. To improve its TMF life, laser texturing at the bond-coat/top coat interface in the CMSX-4 Plus / γ-γ’ BC/ EB-PVD TC system has been investigated.Thanks to the study of the laser-matter interaction, it seems that the different Ni-based single crystal superalloys have similar laser ablation behaviors and they present almost no sub-surface damage after ablation. Nevertheless, the formation of melted matter near created cavities, possibly recrystallized, is often observed.Different patterns (holes, lines, grids) have been…