Search results for " Crystal"
showing 10 items of 3073 documents
Persistence of orographic mixed‐phase clouds
2016
Mixed-phase clouds (MPCs) consist of ice crystals and supercooled water droplets at temperatures between 0 and approximately −38°C. They are thermodynamically unstable because the saturation vapor pressure over ice is lower than that over supercooled liquid water. Nevertheless, long-lived MPCs are ubiquitous in the Arctic. Here we show that persistent MPCs are also frequently found in orographic terrain, especially in the Swiss Alps, when the updraft velocities are high enough to exceed saturation with respect to liquid water allowing simultaneous growth of supercooled liquid droplets and ice crystals. Their existence is characterized by holographic measurements of cloud particles obtained …
An Estimate of Global, Regional and Seasonal Cirrus Cloud Radiative Effects Contributed by Homogeneous Ice Nucleation
2020
There are two fundamental mechanisms through which cirrus clouds form; homo- and heterogeneous ice nucleation (henceforth hom and het). The relative contribution of each mechanism to ice crystal production often determines the microphysical and radiative properties of a cirrus cloud. This study attempts to estimate the radiative contribution of hom relative to het by constraining the cloud microphysics in a climate model to conform with satellite retrievals of cirrus cloud effective diameter De, where the sampled cirrus cloud base had a temperature T Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation) satellite retrievals for cirrus clouds are compared against an updat…
Ray optics for absorbing particles with application to ice crystals at near-infrared wavelengths
2018
Abstract Light scattering by particles large compared to the wavelength of incident light is traditionally solved using ray optics which considers absorption inside the particle approximately, along the ray paths. To study the effects rising from this simplification, we have updated the ray-optics code SIRIS to take into account the propagation of light as inhomogeneous plane waves inside an absorbing particle. We investigate the impact of this correction on traditional ray-optics computations in the example case of light scattering by ice crystals through the extended near-infrared (NIR) wavelength regime. In this spectral range, ice changes from nearly transparent to opaque, and therefore…
Implementation of a comprehensive ice crystal formation parameterization for cirrus and mixed-phase clouds in the EMAC model (based on MESSy 2.53)
2018
A comprehensive ice nucleation parameterization has been implemented in the global chemistry-climate model EMAC to improve the representation of ice crystal number concentrations (ICNCs). The parameterization of Barahona and Nenes (2009, hereafter BN09) allows for the treatment of ice nucleation taking into account the competition for water vapour between homogeneous and heterogeneous nucleation in cirrus clouds. Furthermore, the influence of chemically heterogeneous, polydisperse aerosols is considered by applying one of the multiple ice nucleating particle parameterizations which are included in BN09 to compute the heterogeneously formed ice crystals. BN09 has been modified in order to co…
Strongly SiO2-undersaturated, CaO-rich kamafugitic Pleistocene magmatism in Central Italy (San Venanzo volcanic complex) and the role of shallow dept…
2020
The Pleistocene (~460–265 ka) San Venanzo volcanic complex belongs to the IAP (Intra-Apennine Province) in central Italy, which comprises at least four small Pleistocene monogenetic volcanoes plus several unrooted pyroclastic deposits with peculiar mineralogical and whole-rock chemical compositions. San Venanzo products are strongly SiO2-undersaturated, CaO- and MgO-rich and show ultrapotassic serial character. The relatively common occurrence of calcite in the pyroclastic rocks and the overall high CaO content are interpreted in literature as primary mineral. The main rock facies at San Venanzo are calcite-rich scoria and lapilli tuffs, with minor massive lava flows, and a rare pegma…
Unsupervised Classification of Acoustic Echoes from Two Krill Species in the Southern Ocean (Ross Sea)
2021
This work presents a computational methodology able to automatically classify the echoes of two krill species recorded in the Ross sea employing scientific echo-sounder at three different frequencies (38, 120 and 200 kHz). The goal of classifying the gregarious species represents a time-consuming task and is accomplished by using differences and/or thresholds estimated on the energy features of the insonified targets. Conversely, our methodology takes into account energy, morphological and depth features of echo data, acquired at different frequencies. Internal validation indices of clustering were used to verify the ability of the clustering in recognizing the correct number of species. Th…
Assessment of UV Biological Spectral Weighting Functions for Phenolic Metabolites and Growth Responses in Silver Birch Seedlings
2009
In research concerning stratospheric ozone depletion, action spectra are used as biological spectral weighting functions (BSWFs) for describing the effects of UV radiation on plant responses. Our aim was to evaluate the appropriateness of six frequently used BSWFs that differ in effectiveness with increasing wavelength. The evaluation of action spectra was based on calculating the effective UV radiation doses according to 1-2) two formulations of the generalized plant action spectrum, 3) a spectrum for ultraviolet induced erythema in human skin, 4) a spectrum for the accumulation of a flavonol in Mesembryanthemum crystallinum, 5) a spectrum for DNA damage in alfalfa seedlings and 6) the pla…
Liquid Crystal Phases in Suspensions of Charged Plate-Like Particles
2012
International audience; Anisotropic interactions in colloidal suspensions have recently emerged as a route for the design of new soft materials. Nonisotropic particles can form nematic, smectic, hexatic, and columnar liquid crystals. Although the formation of these phases is well rationalized when excluded volume is solely at play, the role of electrostatic interactions still remains unclear and even less so when particles present a charge heterogeneity, for example, clays. Here, we use Monte Carlo simulations of concentrated suspensions of charged disk-like particles to reveal the role of Coulomb interactions and charge anisotropy underlying liquid crystal formation and structures. We obse…
Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes.
2016
Demonstrated herein are the preparation and crystallographic characterization of the family of fcc silver nanoclusters from Nichol’s cube to Rubik’s cube and beyond via ligand-control (thiolates and phosphines in this case). The basic building block is our previously reported fcc cluster [Ag14(SPhF2)12(PPh3)8] (1). The metal frameworks of [Ag38(SPhF2)26(PR′3)8] (22) and [Ag63(SPhF2)36(PR′3)8]+ (23), where HSPhF2 = 3,4-difluorothiophenol and R′ = alkyl/aryl, are composed of 2 × 2 = 4 and 2 × 2 × 2 = 8 metal cubes of 1, respectively. All serial clusters share similar surface structural features. The thiolate ligands cap the six faces and the 12 edges of the cube (or half cube) while the phosp…
Electron Spin Resonance study of charge trapping in α-ZnMoO4 single crystal scintillator
2015
The origin and properties of electron and hole traps simultaneously appearing in a-ZnMoO4 scintillator after X-ray irradiation at low temperatures (T < 35 K) were studied by Electron Spin Resonance (ESR). ESR spectrum of the electron type trap shows pronounced superhyperfine structure due to the interaction of electron spin with nuclear magnetic moments of 95,97Mo and 67Zn lattice nuclei. Considering the nearly tetragonal symmetry of the center this allows us to identify the electron trap as an electron self-trapped at the (Mo(1)O4) 2 complex. Nearly 60% reduction of the spin–orbit coupling at the Mo(1) ion is caused by the overlap of the Mo and ligand oxygen orbitals indicating an essentia…