Search results for " DSC"

showing 6 items of 16 documents

Calorimetric study of myoglobin embedded in trehalose-water matrixes

2009

It has been suggested that in ‘dry’ protein–trehalose–water systems, water–mediated hydrogen bond network, whose strength increases by drying, anchors the protein to its surroundings. To further characterize this effect, we performed a DSC study on low-water myoglobin–trehalose systems. The denaturation temperature resulted to increase by decreasing hydration, and linearly correlated to the glass transition temperature of both the ternary protein–water–trehalose and the binary water–trehalose systems. Further measurements are being performed to investigate eventual differences among different saccharides.

Ternary numeral systemChemistryHydrogen bondMineralogyCondensed Matter Physicschemistry.chemical_compoundDifferential scanning calorimetryChemical engineeringMyoglobinDenaturation (biochemistry)Physical and Theoretical ChemistryGlass transitionTernary operationThermal analysisdenaturation DSC glass transition myoglobin trehaloseJournal of Thermal Analysis and Calorimetry
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Integrazione di celle fotovoltaiche ibride nel vetromattone

2012

L’invenzione riguarda l’integrazione del vetromattone con celle solari ibride (organiche/inorganiche), conosciute come Dye-sensitized Solar Cell (DSC). La combinazione del vetromattone con le DSC consente di migliorare le prestazioni del prodotto originario rendendolo in grado di produrre energia pulita. Le caratteristiche di trasparenza e isolamento termo-acustico del prodotto possono essere regolate agendo sulla configurazione delle DSC. Il prodotto può essere assemblato a formare pannelli fotovoltaici per la realizzazione di facciate traslucide energeticamente “attive” in varie condizioni luminose (condizioni di luce diffusa o artificiale) e indipendentemente dall’angolo di radiazione so…

The integration of Dye-sensitized Solar Cell (DSC) with the glassblock is disclosed. The combination of the two technological elements the glassblock and the DSC module enhance their own peculiarities. The final complete product is ready-made for installation owns the qualities of the glassblock and produces sustainable energy at the same time. The transparency and the thermo-acoustic insulation may be modulated according to the specific requirements of each case of installation. The product may be used for example to create PV panels for glazed and translucent façades that are able to perform efficiently in all light conditions (even in diffuse light also converting internal artificial light) that are not dependant on the angle of the solar radiation and do not suffer from the high operative temperatures of functioning due to the peculiarities of the DSCs. DSCs are made of economic and biocompatible materials and are produced with low-cost and highly productive printing methods on rigid or flexible substrates. With the integration of DSC modules with the glassblock PV panels coincide with the envelope itself so that they do not need any further structures to be installed on and allow the possibility of subtract from the price of the panel the price of the substituted building element allowing further economies. DSCs can be printed in different colours and with various patterns offering to designers and customers the possibility of intervening on the glassblock aesthetical aspect also taking advantage of the peculiar modularity of the glassblock for larger compositions of drawings on the building’s façade. Seven Hypotheses of integration are discussed in order to obtain DSC-integrated glassblock ready for the construction of a precast and dry-assembled PV panel which can use the horizontal and vertical cavities between the glassblocks to house plastic profiles where the electric interconnections and the steel bars -useful for improve the mechanical resistance of the panel- are integrated.Settore ICAR/10 - Architettura Tecnica
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Differences of stabilized organic carbon fractions and microbiological activity along Mediterranean Vertisols and Alfisols profiles

2010

This study examined the chemical and structural properties of humic substances and microbiological activity in order to verify differences in carbon dynamics along soil profiles in two Vertisols (Typic Haploxerert and Xeric Epiaquert) and two Alfisols (Mollic Haploxeralf and Ultic Haploxeralf) developed under Mediterranean climate in Italy. Humification parameters, thermal methods, including differential scanning calorimetry (DSC) and thermogravimetry (TG), together with Fourier transform infrared (FT-IR) and fluorescence spectroscopies were used to characterize humic acids (HA). Microbiological activity of soils was assessed by basal respiration, metabolic quotient (qCO2) and Cmic:Corg rat…

Total organic carbonChemistrySoil ScienceMineralogyVertisolHumusThermogravimetrySettore AGR/14 - PedologiaSoil pHEnvironmental chemistrySoil waterAlfisolSoil horizonVertisols Alfisols Microbial indices DSC TG FT-IR Fluorescence spectra Humic acidsGeoderma
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Effects of pyrolysis conditions on the thermal transformation of chicken manure into char

2012

Biochar is a fine-grained and highly porous carbonaceous substance, arising from the pyrolitic decomposition of natural or synthetic organic materials. It is lately applied to soils to favorably affect soil physico-chemical properties, such as water and nutrient retention and cation exchange capacity (CEC). The extent of the effect of biochar on crop productivity is very variable due to the different biophysical interactions and processes that occur when it is applied to soils. Char properties are greatly influenced by both natures of feedstock and process conditions. An accurate characterization of biochar is crucial to evaluate the possibility to amend soil with such material by avoiding …

biochar Relaxometry NMR T2 DSC TGA
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Copolymers sensitive to temperature and pH in water and in water+oil mixtures: A DSC, ITC and volumetric study

2011

Block copolymer micelles are receiving an increasing interest because of the variety of structures and the possibilities to tune them by changing external and internal parameters achieving the desired properties for a specific purpose. We have investigated the acid/base behavior, self-assembling and solubilization ability towards polar oils of star-like copolymers named Tetronics. They are composed of branched four-arms each one consisting of two blocks made of EO and PO units linked to the diethylenediamine group, which confers pH response ability. The copolymers T1107 and T90R4 were studied with a sequential and reverse architecture. The thermodynamics of the acid/base equilibrium was stu…

chemistry.chemical_classificationAqueous solutionBase (chemistry)ChemistryCopolymers DSC ITC solubilizationMicelleSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsBiomaterialsColloid and Surface ChemistryDifferential scanning calorimetryMolar volumeChemical engineeringPulmonary surfactantCopolymerOrganic chemistryMacromoleculeJournal of Colloid and Interface Science
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Laponite clay in homopolymer and tri-block copolymer matrices

2007

Macromolecule/laponite nanomaterials were studied by DSC and X-ray diffraction techniques. The matrices are poly(ethylene) glycols at various molecular masses and poly(ethylene oxides)-poly(propylene oxides)-poly(ethylene oxides) tri-block copolymers. The latter were tuned by modulating the molecular masses, at constant hydrophilic/hydrophobic ratio, and the hydrophilicity. For all the investigated systems, the enthalpy of melting (ΔH m) is nearly constant up to a given composition thereafter it increases monotonically reaching the value of the pure macromolecule. We proposed a model to interpret the DSC data. Briefly, it was invoked a mechanism of interaction following which some segments …

chemistry.chemical_classificationMaterials scienceIntercalation (chemistry)EnthalpyPolymerCondensed Matter Physicsdispersion in polymer matrices DSC laponite poly(ethylene)glycols poly(ethylene oxide)poly(propylene oxide)poly(ethylene oxide) X-ray diffractionDifferential scanning calorimetrychemistryChemical engineeringPolymer chemistryX-ray crystallographyCopolymerPhysical and Theoretical ChemistryThermal analysisMacromoleculeJournal of Thermal Analysis and Calorimetry
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