Search results for " Electronics"
showing 10 items of 580 documents
Characterization of Iron−Carbonyl-Protected Gold Clusters
2009
Ligand-stabilized nanometer-sized gold particles are interesting building blocks for molecular electronics, precursors for catalysts, optical labels for biomolecules and diagnosis, and potential nontoxic carriers for therapeutics. In this work we characterize for the first time, by means of near-infrared and Raman spectroscopy and time-dependent density functional calculations, gold clusters protected with iron-carbonyl ligands, such as {Au(22)[Fe(CO)(4)](12)}(6-) shown in the figure. Surprisingly, our results show that these novel compounds bear many analogues to another, well-studied, class of gold clusters, namely those of thiolate-monolayer-protected gold clusters. Our work adds a new d…
Multiple Decay Mechanisms and 2D-UV Spectroscopic Fingerprints of Singlet Excited Solvated Adenine-Uracil Monophosphate
2016
The decay channels of singlet excited adenine uracil monophosphate (ApU) in water are studied with CASPT2//CASSCF:MM potential energy calculations and simulation of the 2D-UV spectroscopic fingerprints with the aim of elucidating the role of the different electronic states of the stacked conformer in the excited state dynamics. The adenine 1La state can decay without a barrier to a conical intersection with the ground state. In contrast, the adenine 1Lb and uracil S(U) states have minima that are separated from the intersections by sizeable barriers. Depending on the backbone conformation, the CT state can undergo inter-base hydrogen transfer and decay to the ground state through a conical …
Voltage Source Multilevel Inverters With Reduced Device Count: Topological Review and Novel Comparative Factors
2021
Multilevel inverters (MLIs) have gained increasing interest for advanced energy-conversion systems due to their features of high-quality produced waveforms, modularity, transformerless operation, voltage, and current scalability, and fault-tolerant operation. However, these merits usually come with the cost of a high number of components. Over the past few years, proposing new MLIs with a lower component count has been one of the most active topics in power electronics. The first aim of this article is to update and summarize the recently developed multilevel topologies with a reduced component count, based on their advantages, disadvantages, construction, and specific applications. Within …
Quasi‐digital front‐ends for current measurement in integrated circuits with giant magnetoresistance technology
2014
In this study, the authors report on two different electronic interfaces for low-power integrated circuits electric current monitoring through current-to-frequency (I-f) conversion schemes. This proposal displays the intrinsic advantages of the quasi-digital systems regarding direct interfacing and self-calibrating capabilities. In addition, as current-sensing devices, they have made use of the giant magnetoresistance (GMR) technology because of its high sensitivity and compatibility with standard complementary metal oxide semiconductor processes. Single elements and Wheatstone bridges based on spin-valves and magnetic tunnel junctions have been considered. In this sense, schematic-level si…
Marginal and Internal Precision of Zirconia Four-Unit Fixed Partial Denture Frameworks Produced Using Four Milling Systems
2021
Background: CAD/CAM systems enable the production of fixed partial dentures with small and reproducible internal and marginal gaps. Purpose: The purpose of this study was to evaluate the reproducibility of the marginal and internal adaptations of four-unit fixed partial denture frameworks produced using four CAD/CAM systems. Materials and Methods: Prepared dies of a master model that simulated the loss of the first left molar were measured. Fifteen frameworks were manufactured using four CAD/CAM systems (A–D). The internal fit was determined by the replica technique, and the marginal gap was determined by microscopy. ANOVA was carried out to detect significant differences, and the Bonferron…
Electroburning of few-layer graphene flakes, epitaxial graphene, and turbostratic graphene discs in air and under vacuum
2015
Graphene-based electrodes are very promising for molecular electronics and spintronics. Here we report a systematic characterization of the electroburning (EB) process, leading to the formation of nanometer-spaced gaps, on different types of few-layer graphene (namely mechanically exfoliated graphene on SiO2, graphene epitaxially grown on the C-face of SiC and turbostratic graphene discs deposited on SiO2) under air and vacuum conditions. The EB process is found to depend on both the graphene type and on the ambient conditions. For the mechanically exfoliated graphene, performing EB under vacuum leads to a higher yield of nanometer-gap formation than working in air. Conversely, for graphene…
Dinuclear Iron(II) Spin Crossover Compounds: Singular Molecular Materials for Electronics
2006
Dinuclear spin crossover molecules can adopt three different spin-pair states: a fully diamagnetic low spin state, [LS–LS], with both iron(II) atoms in the LS state; a paramagnetic mixed spin-pair state [LS–HS]; and an antiferromagnetically coupled [HS–HS] state. Stabilisation of the [LS–HS] state depends on a subtle balance between intra- and inter-molecular interactions in the solid state, consequently, the thermal dependence of the physical and structural properties can present one-step or two-step spin transitions. The former case involves the [LS–LS] ↔ [HS–HS] transformation while in the latter case the intermediate stage responsible for the plateau, at 50% conversion between the two s…
Priority-oriented multicast transmission schemes for heterogeneous traffic in WSNs
2016
To ensure quality of service (QoS) for heterogeneous traffic in IEEE 802.15.4 based wireless sensor networks (WSNs) is a challenging task since no traffic prioritization mechanism is defined in such WSNs. In this paper, we propose two priority-oriented multicast transmission schemes to provide QoS for heterogeneous traffic in WSNs. Contrary to the legacy CSMA/CA and FIFO principles, these schemes differentiate self-generated or received traffic and give priority to delay-sensitive traffic with respect to channel access and packet scheduling. Simulations are performed in order to assess the performance of these schemes in terms of end-to-end delay, energy consumption, packet delivery ratio, …
A Comparative Analysis of Residual Block Alternatives for End-to-End Audio Classification
2020
Residual learning is known for being a learning framework that facilitates the training of very deep neural networks. Residual blocks or units are made up of a set of stacked layers, where the inputs are added back to their outputs with the aim of creating identity mappings. In practice, such identity mappings are accomplished by means of the so-called skip or shortcut connections. However, multiple implementation alternatives arise with respect to where such skip connections are applied within the set of stacked layers making up a residual block. While residual networks for image classification using convolutional neural networks (CNNs) have been widely discussed in the literature, their a…
Large area strip edgeless detectors fabricated by plasma etching process
2007
This work presents the last results from large area edgeless detector, fabricated by Plasma Etching Process to reduce the conventional width of the terminating structure of position sensitive detectors to the detector rim.. A current terminating ring is used to decouple the electrical behavior of the surface from the sensitive volume within a few tens of micrometers. The detectors have been illuminated using an infrared laser and their surface scanned in order to understand their collection behavior at the cut edge. The detectors have very high efficiency up to the insensitive area which is located about 60 mum from the detector edge.