Search results for " Fisica"
showing 10 items of 4804 documents
"Thermal penalty factors" accounting for site topological characteristics in pinch design of Heat Exchanger Networks
2010
Pinch analysis allows to determine targets and solutions for minimum energy requirements in process plants, basing on innovative tools like composite curves and table problem formulation, which ultimately allow generating an optimized heat exchanger network design. On another hand, this technique does not account directly for a number of factors which could play a primary role for the practical feasibility of the network. What if, for instance, once identified an optimal lay-out, we realize that some matches are hardly feasible in practice? Could we adapt the conventional pinch approach to keep into account site topological features since the preliminary design phase? In this paper the auth…
Incorporation mechanism of colloidal TiO2 nanoparticles and their effect on properties of coatings grown on 7075 Al alloy from silicate-based solutio…
2021
Plasma electrolytic oxidation (PEO) was applied using a pulsed unipolar waveform to produce Al2O3-TiO2 composite coatings from sol electrolytic solutions containing colloidal TiO2 nanoparticles. The sol solutions were produced by dissolving 1, 3, and 5 g/L of potassium titanyl oxalate (PTO) in a silicate solution. Scanning electron microscopy, energy dispersive spectrometry, X-ray diffraction, and Raman spectroscopy were applied to characterizing the coatings. Corrosion behavior of the coatings was investigated using polarization and impedance techniques. The results indicated that TiO2 enters the coating through all types of micro-discharging and is doped into the alumina phase. The higher…
Effect of Molybdate on Corrosion Performance of Oxide Coating Produced on 7075 Al Alloy Using PEO
2022
In this research, plasma electrolytic oxidation (PEO) coatings were prepared on 7075 Al alloy in a silicate-based solution with Na2MoO4 additive using a unipolar waveform at constant current density. The coatings displayed micro-pores, micro-cracks, pancake-like and crater-like features, and also solidified molten oxide particles on the surface. The coatings were majorly composed of Al2O3 (γ, δ, and α), SiO2 (amorphous), and MoO3 phases, which confirms the incorporation of molybdenum in the case of additive-containing coatings. Molybdenum species were transported through cracks, channels, and micropores, as the ready access pathways into the coating and partly sealed the c…
Thermal Energy Density Driven Magnetic Reconnection
Magnetic reconnection is usually associated with conversion of magnetic energy into particle acceleration or thermal energy. However, a specific reconnection process driven by plasma pressure gradients was identified in Ref.[1] with a consistent theory of (non-ideal) MHD m0=1 modes in well confined plasmas. This process, based on an Ohm's law contribution to the electron balance equations, remains the basis for the explanation of the observed sawtooth oscillations of the central plasma pressure and for the inferred magnetic field structures due to fishbone oscillations associated with injected high energy particle populations. A novel process [2] expected to have a wide range of application…
Non-Thermal Fusion Burning Plasma Regimes
The Ignitor project is aimed at approaching ignition conditions in Deuterium-Tritium plasmas in order to investigate the issues related to the kind of characteristics of these plasmas, following the line of compact high field opened with the Alcator and Frascati Torus programs, which were capable of producing high density plasma regimes with record confinement properties combined with high degrees of plasma purity. We present a theoretical model describing the emergence of tridimensional structures in magnetically confined plasmas which can significantly change the conditions under which meaningful fusion burn conditions can be reached. These structures can be said to consist of "captive ba…
Cyclical generation of reconnected magnetic fields by electron pressure gra-dients
2021
The theoretical basis for the cyclical generation of macroscopic reconnected magnetic fields in low collisionality plasma regimes is formulated. The relevant process is sustained by the “thermal” energy of the electron population.In particular, an oscillatory mode propagating along and across a confining magnetic field is identified that involves the magnetic reconnection region where the ratio of the longitudinal to transverse electron thermal conductivity is relatively large. A periodic exchange of reconnected magnetic field conductivity energy with electron thermal energy is sustained within a region that remains significant even when the magnetic field configuration from which the mode …
Plasma polymer films and gold nanoparticles: coupling of properties to design a biosensor
The present investigation deals with the functionalization of gold nanoparticles (Au NPs) with primary amine-based plasma polymer films (NH2-PPF), to improve their properties for bioanalytical applications. Cyclopropylamine (CPA) plasma polymerization, in pulsed and continuous wave radio frequency discharges, was employed to growth CPA amino-based PPFs coatings (18 nm) onto Au NPs of 12 nm of diameter deposited on glass and silicon substrates. A multi-technique investigation, based on FT-IR and XPS spectroscopies, AFM and SEM microscopies and Tof-SIMS spectrometry, revealed peculiar features of the CPA PPFs. In particular, by FT-IR it was possible to obtain an overview about the rich chemis…
Solution processes for plastic thin film transistors
2009
Preparazione e caratterizzazione di nanocompositi strutturali costituiti da poliammide e carbonio nanostrutturato
2014
L’obiettivo della presente tesi di dottorato è stato la preparazione e la caratterizzazione di nanocompositi a matrice polimerica contenenti forme allotropiche del carbonio nanostrutturato; tali materiali, grazie alle particolari caratteristiche meccaniche e di rinforzo, trovano applicazione nella fabbricazione di speciali dispositivi individuali come guanti, elmetti, corpetti, etc... Sono state preparate fibre di poliammide (PA) contenenti carbon black (CB), nanoplacchette di grafite (GNP) e nanotubi di carbonio (CNT); per questi ultimi sono stati valutati, inoltre, gli effetti delle loro dimensioni e della funzionalizzazione della loro superficie sulle proprietà di rinforzo dei nanocompos…