Search results for " Fixed"

showing 10 items of 248 documents

Half-width plots, a simple tool to predict peak shape, reveal column kinetics and characterise chromatographic columns in liquid chromatography: Stat…

2013

Peak profiles in chromatography are characterised by their height, position, width and asymmetry; the two latter depend on the values of the left and right peak half-widths. Simple correlations have been found between the peak half-widths and the retention times. The representation of such correlations has been called half-width plots. For isocratic elution, the plots are parabolic, although often, the parabolas can be approximated to straight-lines. The plots can be obtained with the half-widths/retention time data for a set of solutes experiencing the same kinetics, eluted with a mobile phase at fixed or varying composition. When the analysed solutes experience different resistance to mas…

Peak profiles in chromatography are characterised by their height position width and asymmetry; the two latter depend on the values of the left and right peak half-widths. Simple correlations have been found between the peak half-widths and the retention times. The representation of such correlations has been called half-width plots. For isocratic elution the plots are parabolic although often the parabolas can be approximated to straight-lines. The plots can be obtained with the half-widths/retention time data for a set of solutes experiencing the same kinetics eluted with a mobile phase at fixed or varying composition. When the analysed solutes experience different resistance to mass transfer the plots will be solute dependent and should be obtained with the data for each solute eluted with mobile phases at varying composition. The half-width plots approach is a simple tool that facilitates the prediction of peak shape (width and asymmetry) with optimisation purposes reveal the interaction kinetics of solutes in different columns and characterise chromatographic columns. This work shows half-width plots for different situations in isocratic elution including the use of different flows the effect of temperature the modification of the stationary phase surface by an additive the existence of specific interactions within the column and the comparison of columns. The adaptation to gradient elution is also described. Previous knowledge on half-width plots is structured and analysed to which new results are added.Work (thermodynamics)Column characterisationmedia_common.quotation_subjectKineticsLiquid chromatographyAnalytical chemistryHalf-widthsInteraction kineticsBiochemistryAsymmetryAnalytical ChemistryPeak shapeColumn (typography)Position (vector)Mass transferPhase (matter)media_commonChromatographyElutionChemistryOrganic ChemistryGeneral MedicineModels TheoreticalKineticsPredictionChromatography LiquidJournal of Chromatography A
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Clinical outcomes of veneered zirconia anterior partial fixed dental prostheses: A 12-year prospective clinical trial

2019

Abstract Statement of problem Anterior veneered zirconia partial fixed dental prostheses (FDPs) have substituted for metal-ceramic to improve esthetics and biocompatibility. However, the material is susceptible to aging or hydrothermal degradation and to chipping of the feldspathic veneer. Whether these susceptibilities limit the clinical performance of anterior veneered zirconia FPDs is unclear. Purpose The purpose of this prospective clinical study was to analyze the mechanical and biologic behavior of zirconia partial FDPs in the anterior region over a 12-year follow-up period. Material and methods Twenty-seven 3- to 6-unit FDPs fabricated from zirconia veneered with feldspathic porcelai…

Periapical pathologyDentistryDental CariesEsthetics DentalAnterior regionDental Materials03 medical and health sciences0302 clinical medicinePeriodontal diseaseHumansMedicineDental Restoration FailureProspective StudiesSurvival rateBiological Productsbusiness.industryDental prosthesisClinical performance030206 dentistryDental PorcelainClinical trialDental VeneersDenture Partial FixedZirconiumOral SurgeryComplicationbusinessThe Journal of Prosthetic Dentistry
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Solids and Hydraulic Retention Time Effect on N2O Emission from Moving-Bed Membrane Bioreactors

2018

Biological nutrient removal was operated at different solids (SRT) and hydraulic retention times (HRT) in order to assess their influence on nitrous oxide (N2O) emission from a hybrid moving-bed membrane bioreactor. The observed results show that the N2O production decreased when the SRT/HRT was decreased. The maximum N2O gaseous concentration was measured in the aerobic reactor at the end of phase I, and it decreased through phases II and III. From mass balances over the reactors of the system, the aerated (aerobic and membrane) reactors were the largest producers of N2O, showing that the greater part of N2O was produced during the nitrification process.

Petroleum engineeringHydraulic retention timeBiological nutrient removalSettore ICAR/03 - Ingegneria Sanitaria-AmbientaleChemistryGeneral Chemical Engineering0208 environmental biotechnologyN2OChemistry (all)02 engineering and technologyGeneral Chemistry010501 environmental sciences01 natural sciencesIndustrial and Manufacturing Engineering020801 environmental engineeringMembraneSolids retention timeBioreactorIntegrated fixed-film activated-sludge membrane bioreactorChemical Engineering (all)Moving bedHydraulic retention time0105 earth and related environmental sciences
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Polarization shaping for unidirectional rotational motion of molecules.

2015

Control of the orientation of the angular momentum of linear molecules is demonstrated by means of laser polarization shaping. For this purpose, we combine two orthogonally polarized and partially time-overlapped femtosecond laser pulses so as to produce a spinning linear polarization which in turn induces unidirectional rotation of N2 molecules. The evolution of the rotational response is probed by a third laser beam that can be either linearly or circularly polarized. The physical observable is the frequency shift imparted to the probe beam as a manifestation of the angular Doppler effect. Our experimental results are confirmed by theoretical computations, which allow one to gain a deep p…

PhysicsAngular momentumLinear polarizationbusiness.industryRotation around a fixed axisGeneral Physics and AstronomyLinear molecular geometryLaserPolarization (waves)law.inventionsymbols.namesakeOpticslawFemtosecondsymbolsAtomic physicsbusinessDoppler effectPhysical review letters
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Asymptotic freedom in massive Yang-Mills theory

2007

An effective field theory model of the massive Yang-Mills theory is considered. Assuming that the renormalized coupling constants of 'non-renormalizable' interactions are suppressed by a large scale parameter it is shown that in analogy to the non-abelian gauge invariant theory the dimensionless coupling constant vanishes logarithmically for large values of the renormalization scale parameter.

PhysicsCoupling constantNuclear and High Energy PhysicsIntroduction to gauge theoryHigh Energy Physics::LatticeLattice field theoryAsymptotic safety in quantum gravityFOS: Physical sciencesYang–Mills theoryHigh Energy Physics - PhenomenologyHigh Energy Physics::TheoryHigh Energy Physics - Phenomenology (hep-ph)Quantum electrodynamicsEffective field theoryBeta function (physics)Ultraviolet fixed pointMathematical physicsPhysical Review D
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What can be learned from the rotational motion of single molecules in a polymer melt near the glass transition?

2007

We develop a framework for the interpretation of single-molecule (SM) spectroscopy experiments of probe dynamics in a complex glass-forming system. Specifically, from molecular dynamics simulations of a single probe molecule in a coarse-grained model of a polymer melt, we show the emergence of sudden large angular reorientations (SLARs) of the SM as the mode coupling critical temperature is closely approached. The large angular jumps are intimately related to meta-basin transitions in the potential energy landscape of the investigated system and cause the appearance of stretched exponential relaxations of various rotational observables, reported in the SM literature as dynamic heterogeneity…

PhysicsCouplingMolecular dynamicsTime–temperature superpositionCondensed matter physicsDynamics (mechanics)Rotation around a fixed axisGeneral Physics and AstronomyObservableGlass transitionSpectroscopyMolecular physicsEurophysics Letters (EPL)
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Poiseuille flow of a Quincke suspension

2014

The controversy of models of dielectric particle suspensions with antisymmetric stress, which predict a nonphysical cusp of the velocity profile in plane Poiseuille flow under the action of the electrical field, is resolved. In the mean-field approximation, the nonlinear kinetic equation is derived for coupled due to the flow translational and rotational motion of the particles. By its numerical solution, it is shown that the velocity profile is smeared due to the translational diffusion of the particles with opposite directions of rotation. The obtained results for the velocity profiles and flow rates as a function of the electric field strength are in qualitative agreement with the existi…

PhysicsField (physics)ViscosityRotation around a fixed axisMechanicsRotationHagen–Poiseuille equationKineticsMotionNonlinear DynamicsSuspensionsFlow (mathematics)Electric ImpedanceParticleDiffusion (business)AlgorithmsComplex fluidPhysical Review E
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R2phase diagram of quantum Einstein gravity and its spectral dimension

2012

Within the gravitational asymptotic safety program, the renormalization group (RG) flow of the ${R}^{2}$ truncation in three and four spacetime dimensions is analyzed in detail. In particular, we construct RG trajectories which emanate from the non-Gaussian UV fixed point and possess long classical regimes where the effective average action is well approximated by the classical Einstein-Hilbert action. As an application we study the spectral dimension of the effective quantum Einstein gravity spacetimes resulting from these trajectories, establishing that the picture of a multifractal spacetime is robust under the extension of the truncated theory space. We demonstrate that regimes of const…

PhysicsGravitationGeneral Relativity and Quantum CosmologyNuclear and High Energy PhysicsSpacetimeGeneral relativityQuantum mechanicsAsymptotic safety in quantum gravityQuantum gravityFixed pointRenormalization groupUltraviolet fixed pointMathematical physicsPhysical Review D
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Ultraviolet Fixed Point and Generalized Flow Equation of Quantum Gravity

2001

A new exact renormalization group equation for the effective average action of Euclidean quantum gravity is constructed. It is formulated in terms of the component fields appearing in the transverse-traceless decomposition of the metric. It facilitates both the construction of an appropriate infrared cutoff and the projection of the renormalization group flow onto a large class of truncated parameter spaces. The Einstein-Hilbert truncation is investigated in detail and the fixed point structure of the resulting flow is analyzed. Both a Gaussian and a non-Gaussian fixed point are found. If the non-Gaussian fixed point is present in the exact theory, quantum Einstein gravity is likely to be r…

PhysicsHigh Energy Physics - TheoryNuclear and High Energy PhysicsInfrared fixed pointAsymptotic safety in quantum gravityGravitonFOS: Physical sciencesGeneral Relativity and Quantum Cosmology (gr-qc)Euclidean quantum gravityRenormalization groupGeneral Relativity and Quantum CosmologyHigh Energy Physics::TheoryGeneral Relativity and Quantum CosmologyClassical mechanicsHigh Energy Physics - Theory (hep-th)Quantum gravityFunctional renormalization groupUltraviolet fixed pointMathematical physics
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Evidence against non-asymptotically-free theories of strong interactions

1977

Abstract It is shown that ultraviolet finite fixed point theories of strong interactions are incompatible with the pattern of scaling deviations in deep inelastic lepton-hadron processes.

PhysicsNuclear and High Energy PhysicsClassical mechanicsHigh Energy Physics::PhenomenologymedicineHigh Energy Physics::ExperimentFixed pointmedicine.disease_causeScalingUltraviolet fixed pointUltravioletPhysics Letters B
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