Search results for " Fuel Cell"

Opportunity of metallic interconnects for ITSOFC : Reactivity and electrical property.

2006

International audience; Iron-base alloys (Fe-Cr) are proposed hereafter as materials for interconnect of planar-type intermediate temperature solid oxide fuel cell (ITSOFC); they are an alternative solution instead of the use of ceramic interconnects. These steels form an oxide layer (chrornia) which protects the interconnect from the exterior environment, but is an electrical insulator. One solution envisaged in this work is the deposition of a reactive element oxide coating, that slows down the formation of the oxide layer and that increases its electric conductivity. The oxide layer, formed at high temperature on the uncoated alloys, is mainly composed of chromia; it grows in accordance …

Main Fuel Cells mathematical models: Comparison and analysis in terms of free parameters

2010

This paper resumes the main mathematical models of Fuel Cells (PEM models). In particular, a comparison study of the various models introduced in the technical literature is presented and the dependency of the various model parameters is analyzed in different operating conditions. As the manifold of the model parameter is very wide and their determination is difficult, it is mandatory to introduce approximations and simplifications on which each model is based. The novelty of this work is the organization of the existing models in three categories with regard to the number of free parameters and to the dependency of such parameters on the different running conditions and the usage of a refe…

Criteri e metodi per l'ottimizzazione di sistemi di poligenerazione di piccola e media taglia - Criteria and methodologies for the optimization of sm…

2011

L'Unione Europea ha individuato nella produzione combinata di energia elettrica e calore una delle tecnologie ad alta efficienza di maggior interesse, fissando per il 2010 il target del 18% della produzione elettrica totale dell'Unione da sistemi cogenerativi (COM/97/0514). Dati recenti rivelano la non attualità di tale target (al 2005 si è raggiunto il 12% di penetrazione); rimane tuttavia evidente la volontà, esistente sia a livello comunitario che in molti Stati Membri, di perseguire la via della promozione della poligenerazione. Le ragioni di questo interesse sono evidenti: l'elevata efficienza di conversione garantita dal recupero dei cascami termici di un ciclo diretto consente, a par…

BIO-ELECTROCHEMICAL SYSTEMS FOR ENERGY GATHERING FROM WASTEWATER

2017

It has been calculated that annually 1.5 × 108 MWh are wasted as municipal, industrial, and animal wastewater. The recovery of at least part of this energy it is of primary importance in order to approach circular economy. As AD, MFC is a biotechnology that uses microorganism into an anaerobic environment for energy conversion and recovery. Differently from AD, MFC belongs to the sub-division of Bio-Electrochemical Systems (BESs), having the advantage to achieve a direct electrical output. Exoelectrogens bacteria are employed, capable to close their respiratory electron chain on the surface of an electrode. Up to know, BESs were used to extract energy from a multitude of wastes, such as dis…

Influence of the methodology of inoculation in the performance of air-breathing microbial fuel cells

2017

In this work, four air-breathing microbial fuel cells (AB-MFC) were operated for 1 month in order to determine if the methodology of inoculation affects the steady-state performance of this type of MFCs. For this purpose, anaerobic and aerobic sludge were fed to two identical AB-MFCs without any external carbon source into a tight sealed environment during the first three days of start-up. For comparison purposes, other two AB-MFCs were operated mixing the initial sludge and an amount of sodium acetate as substrate. Results point out that the inoculation procedure does not affect the steady-state treatment capacity of the cells but it affects very seriously the production of electricity. On…

Abatement of AO7 in a divided microbial fuel cells by sequential cathodic and anodic treatment powered by different microorganisms

2017

Abstract Microbial fuel cells (MFCs) can allow the treatment of organic pollutants resistant to conventional biological processes by electro-Fenton (EF) process performed in the cathodic compartment. However, EF usually results in a partial mineralization of pollutants. Here, we have studied the possible treatment of such organics in a MFC by a sequential cathodic and anodic treatment. In particular, the treatment of an aqueous solution of Acid Orange (AO7), a largely used azoic dye resistant to conventional biological processes, was performed in the cathodic compartment of a divided MFC by EF. The process allowed the total removal of the color and the partial removal of the TOC, due mainly…

Influence of the initial sludge characteristics and acclimation on the longterm performance of double-compartment acetate-fed microbial fuel cells

2018

Abstract In this work, three double-compartment MFCs (DC-MFC) were operated for 1 month in order to compare their performances in terms of wastewater treatment capacity and electricity production and to get information about how this performance is influenced by the start-up procedure. To do this, they underwent different start-up procedures. One of them (aerobic-starved MFC) was inoculated with 100% fresh aerobic sludge, another (anaerobic-starved MFC) using 100% fresh anaerobic sludge, and finally a third one (aerobic-fed MFC) was inoculated using a mixture 10% fresh aerobic sludge and 90% synthetic wastewater (based on acetate). Then, from this start-up, the cells were operated exactly u…

From Microorganism-Based Amperometric Biosensors towards Microbial Fuel Cells

2021

This review focuses on the overview of microbial amperometric biosensors and microbial biofuel cells (MFC) and shows how very similar principles are applied for the design of both types of these bioelectronics-based devices. Most microorganism-based amperometric biosensors show poor specificity, but this drawback can be exploited in the design of microbial biofuel cells because this enables them to consume wider range of chemical fuels. The efficiency of the charge transfer is among the most challenging and critical issues during the development of any kind of biofuel cell. In most cases, particular redox mediators and nanomaterials are applied for the facilitation of charge transfer from a…

Anodic biofilm vitality during operation of microbial fuel cells at various load conditions

2016

Heterogeneous electro-Fenton and photoelectro-Fenton processes: A critical review of fundamental principles and application for water/wastewater trea…

2018

Abstract This exhaustive review focuses on the fundamental principles and applications of heterogeneous electrochemical wastewater treatment based on Fenton’s chemistry reaction. The elementary equations involved in formation of hydroxyl radical in homogeneous electro-Fenton (EF) and photo electro-Fenton (PEF) processes was presented and the advantages of using insoluble solids as heterogeneous catalyst rather than soluble iron salts (heterogeneous electro-Fenton process) (Hetero-EF) was enumerated. Some of the required features of good heterogeneous catalysts were discussed, followed by the mechanisms of catalytic activation of H2O2 to reactive oxygen species (ROS) especially hydroxyl radi…