Search results for " Gradient"
showing 10 items of 575 documents
In situ synchrotron characterization of mechanically activated self-propagating high-temperature synthesis applied in Mo–Si system
1999
Abstract An original experiment was designed to monitor structural and thermal evolutions during the MASHS (Mechanically Activated Self-propagating High-temperature Synthesis) process in the Mo–Si system. Time-Resolved X-Ray Diffraction (TRXRD) coupled with an infrared imaging technique was performed to study, in situ, the formation of the α-MoSi2 phase in the combustion front. Despite a temporal resolution of 50 ms between two consecutive diffractograms, no intermediate phase was observed during the passage of the combustion front. The only reaction responsible for the self-sustentation is Mo+2Si→MoSi2 in the primary zone inside the combustion wave. The mechanical activation was found to i…
Fluid reservoirs in the crust and mechanical coupling between the upper and lower crust
2004
An important observation associated with seismic activity on the Nagamachi-Rifu Fault is the existence of tabular, fluid rich zones at mid-crustal levels. These zones resemble the “bright spots” seen in many seismic images of the crust worldwide. The aim of this paper is to develop the mechanical foundations for the formation of such zones. To do so requires an understanding of the distribution of pore fluid pressure in a deforming crust. In a hydrostatically stressed porous material, the pore fluid pressure should equal the mean stress in order to keep the pores from collapsing. Past discussions of this subject imply very high pore fluid pressures, two to three times lithostatic. Considera…
Multiple solutions for a Dirichlet problem with p-Laplacian and set-valued nonlinearity
2008
AbstractThe existence of a negative solution, of a positive solution, and of a sign-changing solution to a Dirichlet eigenvalue problem with p-Laplacian and multi-valued nonlinearity is investigated via sub- and supersolution methods as well as variational techniques for nonsmooth functions.
Elliptic equations having a singular quadratic gradient term and a changing sign datum
2012
In this paper we study a singular elliptic problem whose model is \begin{eqnarray*} - \Delta u= \frac{|\nabla u|^2}{|u|^\theta}+f(x), in \Omega\\ u = 0, on \partial \Omega; \end{eqnarray*} where $\theta\in (0,1)$ and $f \in L^m (\Omega)$, with $m\geq \frac{N}{2}$. We do not assume any sign condition on the lower order term, nor assume the datum $f$ has a constant sign. We carefully define the meaning of solution to this problem giving sense to the gradient term where $u=0$, and prove the existence of such a solution. We also discuss related questions as the existence of solutions when the datum $f$ is less regular or the boundedness of the solutions when the datum $f \in L^m (\Omega)$ with …
Existence and comparison results for a singular semilinear elliptic equation with a lower order term
2014
This paper deals with the homogeneous Dirichlet problem for a singular semilinear elliptic equation with a first order term. When the datum is bounded we prove an existence result and we show that any solution can be compared with the solution to a suitable symmetrized problem.
From the Golgi-Cajal mapping to the transmitter-based characterization of the neuronal networks leading to two modes of brain communication: Wiring a…
2007
After Golgi-Cajal mapped neural circuits, the discovery and mapping of the central monoamine neurons opened up for a new understanding of interneuronal communication by indicating that another form of communication exists. For instance, it was found that dopamine may be released as a prolactin inhibitory factor from the median eminence, indicating an alternative mode of dopamine communication in the brain. Subsequently, the analysis of the locus coeruleus noradrenaline neurons demonstrated a novel type of lower brainstem neuron that monosynaptically and globally innervated the entire CNS. Furthermore, the ascending raphe serotonin neuron systems were found to globally innervate the forebrai…
In vitro study of N-succinyl chitosan for targeted delivery of 5-aminosalicylic acid to colon
2011
In vitro study on N-succinyl chitosan and chitosan (control) matrices for selective colon delivery of 5-aminosalicylic acid is described. Matrices containing β-cyclodextrin were also prepared. As shown by DSC analyses, the drug was successfully loaded into the matrices reaching up to 95% entrapment efficiency. Swelling and drug release were studied at pH 1.2, pH 7.4, and in a pH gradient medium to simulate the gastro-intestinal transit. Main result of this study was a higher capability of N-succinyl chitosan alone to better control drug release in the simulated gastro-intestinal transit: N-succinyl chitosan gave the lowest release in acid medium (≅15%) and the highest in alkaline environmen…
Photophysical Properties of Charged Cyclometalated Ir(III) Complexes: A Joint Theoretical and Experimental Study
2011
The photophysical properties of a series of charged biscyclometalated [Ir(ppy)(2)(N boolean AND N)](1+) complexes, where ppyH is 2-phenylpyridine and N boolean AND N is 2,2'-bipyridine (bpy), 6-phenyl-2,2'-bipyridine (pbpy), and 6,6'-dipheny1-2,2'-bipyridine (dpbpy) for complexes 1, 2, and 3, respectively, have been investigated in detail. The photoluminescence performance in solution decreases from 1 to 3 upon attachment of phenyl groups to the ancillary ligand. The absorption spectra recorded over time suggest that complex 3 is less stable compared to complexes 1 and 2 likely due to a nucleophilic-assisted ancillary ligand-exchange reaction. To clarify this behavior, the temperature depen…
Mechanism of the Citrate Transporters in Carbohydrate and Citrate Cometabolism in Lactococcus and Leuconostoc Species
1998
ABSTRACT Citrate metabolism in the lactic acid bacterium Leuconostoc mesenteroides generates an electrochemical proton gradient across the membrane by a secondary mechanism (C. Marty-Teysset, C. Posthuma, J. S. Lolkema, P. Schmitt, C. Divies, and W. N. Konings, J. Bacteriol. 178:2178–2185, 1996). Reports on the energetics of citrate metabolism in the related organism Lactococcus lactis are contradictory, and this study was performed to clarify this issue. Cloning of the membrane potential-generating citrate transporter (CitP) of Leuconostoc mesenteroides revealed an amino acid sequence that is almost identical to the known sequence of the CitP of Lactococcus lactis . The cloned gene was exp…
Helium isotope systematics of volcanic gases and thermal waters of Guadeloupe Island, Lesser Antilles
2014
Abstract The island of Guadeloupe is located in the middle of the 850 km long Lesser Antilles island arc. Present-day volcanic and geothermal activity is concentrated in two systems both located in the southwestern part of the island (Basse Terre): the La Soufriere volcanic complex and the Bouillante hydrothermal system, some 20 km to the northwest of the volcano. We report here the largest isotopic data set for helium isotopes in hydrothermal gases and waters from both systems, acquired between 1980 and 2012. 3 He/ 4 He ratios in the fumarolic gases of La Soufriere volcano have been quite homogeneous and stable over the last thirty years. The average ratio of 8.2 ± 0.2 R a confirms that th…