Search results for " IRR."

Blue luminescent amino-functionalized graphene quantum dots as a responsive material for potential detection of metal ions and malathion

2022

Large amounts of hazardous and toxic substances in the environment require non-toxic, cheap, easy, rapid, and sensitive methods for their detection. Blue luminescent graphene quantum dots (GQDs) were produced by electrochemical cleavage of graphite electrodes followed by gamma irradiation in the presence of ethylenediamine (EDA). Modified dots were able to detect metal ions (Co2+, Pd2+, Fe3+) due to photoluminescence quenching. The highest sensitivity was detected for the sample irradiated at a dose of 25 kGy. The limits of detection (LODs) were 1.79, 2.55, and 0.66 μmol L−1 for Co2+, Fe3+, and Pd2+, respectively. It was observed that GQDs irradiated at 200 kGy act as an ultra-sensitive tur…

A procedure to calculate the I–V characteristics of thin-film photovoltaic modules using an explicit rational form

2015

Abstract Accurate models of the electrical behaviour of photovoltaic modules are effective tools for system design. One or two diode equivalent circuits have been widely used even though some mathematical difficulties were found dealing with implicit equations. In this paper, a new model based on a simple rational function, which does not contain any implicit exponential form, is presented. The model was conceived in order to be used with thin-film photovoltaic modules, whose current–voltage curves are characterised by very smooth shapes. The parameters of the model are evaluated by means of the derivatives of the issued characteristics in the short circuit and open circuit points at standa…

A procedure to evaluate the seven parameters of the two-diode model for photovoltaic modules

2019

Abstract The paper presents an analytical procedure to calculate the seven parameters of the two-diode model of photovoltaic (PV) panels for any value of the solar irradiance and cell temperature. Six parameters (the photocurrent, the diode reverse saturation currents, the quality factor of the first diode and the series and shunt resistances), are evaluated by solving the equations related to the properties of the main points of the current-voltage (I-V) characteristics. The further information, necessary to calculate the entire set of seven truly independent parameters, is based on two conditions that have to be simultaneously satisfied: 1) the exclusion of negative values of the model pa…

An accurate one-diode model suited to represent the current-voltage characteristics of crystalline and thin-film photovoltaic modules

2020

Abstract In this paper a new one-diode model, conceived in order to be used to represent the current-voltage curves of both crystalline and thin-film photovoltaic modules, is presented. The model parameters are calculated from the information contained in the datasheets issued by manufactures by means of simple iterative procedures that do not require the assumption of simplifying hypotheses. Some innovative relations describing the dependence of the parameters from the solar irradiance and cell temperature are adopted in order to permit the model to reliably simulate the electrical behaviour of photovoltaic devices operating in real conditions. The ability of the model to calculate the cur…

Development of a test station for accurate in situ I-V curve measurements of photovoltaic modules in Southern Norway

2011

The development of an outdoor test station for accurate in situ I-V curve measurements of photovoltaic (PV) modules is described. The modules are installed in an open-rack configuration at the University of Agder in Southern Norway. Seven new and three aged PV modules of different type and make are being tested, including mono-and multicrystalline silicon from differing manufacturing routes, triple-junction amorphous silicon, and CIS. Data acquisition is controlled with a multichannel electronic load system and LabVIEW software, recording high-resolution I-V curves at one-minute intervals. Between I-V curve sweeps, each module is operated at the maximum power point. Characteristic electrica…

Uso di formulazioni della metodologia cream per la trattazione dell’errore umano nella valutazione ad alberi di guasto della probabilita’ di esposizi…

2008

Turning lipophilic phthalocyanines/TiO2 composites into efficient photocatalysts for the conversion of CO2 into formic acid under UV–vis light irradi…

2014

Metal-free, Cu(II)- or Zn(II) tetrakis [4-(2,4-bis-(1,1-dimethylpropyl)phenoxy)]phthalocyanines loaded over TiO2 (anatase) proved to be active in the photoreduction of CO2 to formic acid (HCO2H) in water under UV-vis light. CuPc/TiO2 is catalyst of choice, allowing to reach a maximum yield of HCO2H, unequalled by any other similar catalytic systems. Because of their low environmental impact, low potential cost, and efficient power conversion, these multipurpose materials show promise in the setup of sustainable methods for CO2 valorization. (C) 2014 Elsevier B.V. All rights reserved.

Intralaboratory validation of four in vitro assays for the prediction of the skin sensitizing potential of chemicals

2011

Abstract Allergic contact dermatitis is induced by repeated skin contact with an allergen. Assessment of the skin sensitizing potential of chemicals, agrochemicals, and especially cosmetic ingredients is currently performed with the use of animals. Animal welfare and EU legislation demand animal-free alternatives reflected in a testing and marketing ban for cosmetic ingredients beginning in 2013. The underlying mechanisms of induction and elicitation of skin sensitization are complex and a chemical needs to comply several properties being skin sensitizing. To account for the multitude of events in the induction of skin sensitization an in vitro test system will consist of a battery of vario…

Valorization of Wastewater from Table Olives: NMR Identification of Antioxidant Phenolic Fraction and Microwave Single-Phase Reaction of Sugary Fract…

2021

The table olive industry is producing a huge amount of wastewater, which is a post-processing cost and an environmental concern. The present study aims to valorize this processing by-product to obtain a value-added product, thereby enhancing resource efficiency and contributing to achieving sustainable development goals (SDGs). In this sense, a chemical reaction-based platform was developed to obtain valuable components, such as levulinic acid (LA) and 5-hydromethylfurfural (HMF). The products were then analyzed using NMR identification of the antioxidant phenolic fraction and microwave single-phase reaction of the sugary fraction. According to the results, the highest concentration of phen…

The Essential Oil Composition ofEryngium foetidumL. in South Vietnam Extracted by Hydrodistillation under Conventional Heating and Microwave Irradiat…

2008

Abstract Essential oils of Eryngium foetidum L. (Apiaceae) in the South Vietnam isolated by hydrodistillation under conventional heating or microwave irradiation showed somewhat similar in chemical compositions. The microwave method gave a higher extraction yield in a much shorter time frame than the conventional heating protocol. Noticeably, the oil obtained from the microwave method showed a stronger antimicrobial activity than the other. Among all parts of the plant, inflorescence contained the highest oil content, and three-month old plant material was found richest in oil content as well. Physical, chemical and antibacterial properties of the oil products isolated from both methods wer…