Search results for " Ion Exchange"
showing 5 items of 65 documents
Characterization of aquatic humic substances and their metal complexes by immobilized metal-chelate affinity chromatography on iron(III)-loaded ion e…
2001
The analytical fractionation of aquatic humic substances (HS) by means of immobilized metal-chelate affinity chromatography (IMAC) on metal-loaded chelating ion exchangers is described. The cellulose HYPHAN, loaded with different trivalent ions, and the chelate exchanger Chelex 100, loaded to 90% of its capacity with Fe(III), were used. The cellulose HYPHAN, loaded with 2% Fe(III), resulted in HS distribution coefficients Kd of up to 10(3.7) mL/g at pH 4.0 continuously decreasing down to 10(1.5) at pH 12, which were appropriate for HS fractionation by a pH-depending chromatographic procedure. Similar distribution coefficients Kd were obtained for HS sorption onto Fe(III)-loaded Chelex 100. …
Performance analysis of the first Reverse Electrodialysis prototype plant operating with natural brackish water and salt pond brine
2014
Reverse Electrodialysis (RED) has gained a strong interest among the salinity gradient energy technologies during the last years. Recently, notable improvements have been reached in terms of membranes and stack performances using artificial solutions. However, the use of real saline solutions strongly affects the process performance, requiring additional R&D efforts for a successful scale-up of such technology. This work focuses on the experimental campaign performed on the first RED prototype plant fed with real brackish water and saltworks brine. The plant is located within the Ettore e Infersa saltworks in Marsala (TP, South of Italy). It is the final accomplishment of the REAPower proje…
Optimisation analysis of Reverse Electrodialysis systems for power production from concentrated brines
2016
Reverse Electrodialysis (RED) is rapidly growing as technology to produce electric energy by mixing saline solutions with different salinity. Recent developments have shown promising results on real site installations, demonstrating the feasibility of the RED process on the pilot scale. Therefore, further modelling efforts are now needed to optimise the technology, in order to enhance the performance. In this work, an optimisation study for the RED process is presented, taking into account saline waters and concentrated brine as feed streams. The model, which is developed within GAMS environment, predicts the optimal set of process variables that maximise the process yield, as well as the g…
Power Production from Produced Waters via Reverse Electrodialysis: A Preliminary Assessment
2022
Wastewaters generated by crude oil extraction processes, called “produced waters” (PWs), are complex solutions that contain organic compounds, mainly hydrocarbons, and often exhibit high salinity. The large amounts of PWs represent a global issue because of their environmental impact. An approach widely used in the oil industry is the reinjection of this wastewater into the extraction wells after a suitable treatment. The high salt concentration of such solutions may be used in salinity gradient technologies to produce green electricity. Among these technologies, reverse electrodialysis (RED) is one of the most promising. In this work, the application of RED for energy generatio…
An Ion Exchange Membrane Crystallisation reactor for Magnesium recovery from brines
2015
CrIEM technology is a novel ion exchange application that allows reactive crystallization for separation of valuable species (e.g. Mg from brines) with a large flexibility in the choice of reactants.